Recognition in the domain of molecular chirality: from noncovalent interactions to separation of enantiomers
It is not a coincidence that both chirality and noncovalent interactions are ubiquitous in
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …
nature and synthetic molecular systems. Noncovalent interactivity between chiral molecules …
Recent Advances in Chiral Selectors Immobilization and Chiral Mobile Phase Additives in Liquid Chromatographic Enantio-separations; A Review
For decades now, the separation of chiral enantiomers of drugs has been gaining the
interest and attention of researchers. In 1991, the first guidelines for development of chiral …
interest and attention of researchers. In 1991, the first guidelines for development of chiral …
Interrogating the CISS effect in chiral and paramagnetic organic radicals: the impact of the molecular spin over the total spin polarization
JA De Sousa, P Mayorga-Burrezo… - Journal of Materials …, 2024 - pubs.rsc.org
Continuous research on new chiral molecular materials brings new exciting properties to the
field of molecular electronics. The discovery of the chirality-induced spin selectivity (CISS) …
field of molecular electronics. The discovery of the chirality-induced spin selectivity (CISS) …
[HTML][HTML] Unravelling dispersion forces in liquid-phase enantioseparation. Part I: Impact of ferrocenyl versus phenyl groups
Background Highly ordered chiral secondary structures as well as multiple (tunable)
recognition sites are the keys to success of polysaccharide carbamate-based chiral …
recognition sites are the keys to success of polysaccharide carbamate-based chiral …
[HTML][HTML] Chiral separation of oxazolidinone analogues by liquid chromatography on polysaccharide stationary phases using polar organic mode
The enantioseparation of four oxazolidinone and one biosimilar thiazolidine derivatives was
performed on seven different polysaccharide-type chiral stationary phases (Lux Amylose-1 …
performed on seven different polysaccharide-type chiral stationary phases (Lux Amylose-1 …
Enantioseparation of 5, 5′-dibromo-2, 2′-dichloro-3-selanyl-4, 4′-bipyridines on polysaccharide-based chiral stationary phases: Exploring chalcogen bonds in …
The chalcogen bond (ChB) is a noncovalent interaction based on electrophilic features of
regions of electron charge density depletion (σ-holes) located on bound atoms of group VI …
regions of electron charge density depletion (σ-holes) located on bound atoms of group VI …
Unravelling functions of halogen substituents in the enantioseparation of halogenated planar chiral ferrocenes on polysaccharide-based chiral stationary phases …
Planar chiral halogenated ferrocenes have come in useful as synthetic intermediates over
the years, allowing for the preparation of functionalized derivatives for catalysis, material …
the years, allowing for the preparation of functionalized derivatives for catalysis, material …
[HTML][HTML] Enantioseparation of new axially chiral carboxylic acids on polysaccharide-based chiral stationary phases under normal phase elution conditions
In the last decade, the availability of new and versatile synthetic strategies for the
preparation of substituted 4, 4'-bipyridyl derivatives based on chemo-and regioselective …
preparation of substituted 4, 4'-bipyridyl derivatives based on chemo-and regioselective …
[HTML][HTML] Exploring interaction modes between polysaccharide-based selectors and biologically active 4, 4′-bipyridines by experimental and computational analysis
In the last few years, chiral 4, 4′-bipyridine derivatives have been developed for different
applications in catalysis, enantioseparation science, supramolecular and theoretical …
applications in catalysis, enantioseparation science, supramolecular and theoretical …
Comparative enantioseparation of planar chiral ferrocenes on polysaccharide‐based chiral stationary phases
Planar chiral ferrocenes are well‐known compounds that have attracted interest for
application in synthesis, catalysis, material science, and medicinal chemistry for several …
application in synthesis, catalysis, material science, and medicinal chemistry for several …