The electronic structure of transition metal oxides for oxygen evolution reaction

H Wang, KHL Zhang, JP Hofmann… - Journal of Materials …, 2021 - pubs.rsc.org
Electrolysis of water to produce hydrogen and oxygen is a promising pathway for the storage
of renewable energy in form of chemical fuels. The efficiency of the overall process is usually …

Progress in the studies of electronic and magnetic properties of layered MPX3 materials (M: transition metal, X: chalcogen)

Y Dedkov, Y Guo, E Voloshina - Electronic Structure, 2023 - iopscience.iop.org
The recent progress in the studies of 2D materials placed in front many experimental and
theoretical works on the interesting class of materials, the so-called transition metal …

Giant Magnetic Anisotropy in the Atomically Thin van der Waals Antiferromagnet FePS3

Y Lee, S Son, C Kim, S Kang, J Shen… - Advanced Electronic …, 2023 - Wiley Online Library
Van der Waals (vdW) magnets are an ideal platform for tailoring 2D magnetism with
immense potential for spintronics applications and are intensively investigated. However …

Large Orbital Magnetic Moment in VI3

D Hovancik, J Pospisil, K Carva, V Sechovsky… - Nano Letters, 2023 - ACS Publications
The existence of the V3+-ion orbital moment is an open issue of the nature of magnetism in
the van der Waals ferromagnet VI3. The huge magnetocrystalline anisotropy in conjunction …

Mechanochemical approach towards optimized Ni2+ spin configuration in NiO/TiO2 heterojunction with enhanced solar-driven H2 photoproduction

E do Couto-Pessanha, VM Paiva, TJA Mori… - International Journal of …, 2024 - Elsevier
A mechanochemical approach through ball milling (BM) to produce NiO clusters supported
on TiO 2 has been successfully applied, resulting in a NiO/TiO 2 pn heterojunction as an …

Advances in the OCEAN-3 spectroscopy package

J Vinson - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
The OCEAN code for calculating valence-and core-level spectra using the Bethe-Salpeter
equation is briefly reviewed. OCEAN is capable of calculating optical absorption, near-edge …

Computational approaches for XANES, VtC-XES, and RIXS using linear-response time-dependent density functional theory based methods

DR Nascimento, N Govind - Physical Chemistry Chemical Physics, 2022 - pubs.rsc.org
The emergence of state-of-the-art X-ray light sources has paved the way for novel
spectroscopies that take advantage of their atomic specificity to shed light on fundamental …

Interpreting the Cu–O2 Antibonding Nature in Two Cu–O2 Complexes from Cu L-Edge X-ray Absorption Spectra

SY Wang, JR Zhang, M Guo, W Hua - Inorganic Chemistry, 2023 - ACS Publications
Cu–O2 structures play important roles in bioinorganic chemistry and enzyme catalysis,
where the bonding between the Cu and O2 parts serves as a fundamental research …

X-ray absorption spectra of f-element complexes: insight from relativistic multiconfigurational wavefunction theory

DC Sergentu, J Autschbach - Dalton Transactions, 2022 - pubs.rsc.org
X-ray absorption near edge structure (XANES) spectroscopy, coupled with ab initio
calculations, has emerged as the state-of-the-art tool for elucidating the metal-ligand …

Soft X-ray signatures of cationic manganese–oxo systems, including a high-spin manganese (v) complex

MG Delcey, R Lindblad, M Timm, C Bülow… - Physical Chemistry …, 2022 - pubs.rsc.org
Manganese–oxo species catalyze key reactions, including C–H bond activation or dioxygen
formation in natural photosynthesis. To better understand relevant reaction intermediates …