Toolbox for distal C–H bond functionalizations in organic molecules

SK Sinha, S Guin, S Maiti, JP Biswas, S Porey… - Chemical …, 2021 - ACS Publications
Transition-metal-catalyzed C–H activation has developed a contemporary approach to the
omnipresent area of retrosynthetic disconnection. Scientific researchers have been tempted …

Advances on the merger of electrochemistry and transition metal catalysis for organic synthesis

CA Malapit, MB Prater, JR Cabrera-Pardo, M Li… - Chemical …, 2021 - ACS Publications
Synthetic organic electrosynthesis has grown in the past few decades by achieving many
valuable transformations for synthetic chemists. Although electrocatalysis has been popular …

Strategic evolution in transition metal-catalyzed directed C–H bond activation and future directions

S Rej, A Das, N Chatani - Coordination Chemistry Reviews, 2021 - Elsevier
In the field of C–H bond functionalization chemistry, directed C–H bond activation strategies
are highly appreciated due to the high efficiency and selectivity of such reactions towards a …

Electrocatalytic C–H Activation

N Sauermann, TH Meyer, Y Qiu, L Ackermann - Acs Catalysis, 2018 - ACS Publications
C–H activation has emerged as a transformative tool in molecular synthesis, but until
recently oxidative C–H activations have largely involved the use of stoichiometric amounts of …

Beyond C2 and C3: transition-metal-catalyzed C–H functionalization of indole

JA Leitch, Y Bhonoah, CG Frost - ACS Catalysis, 2017 - ACS Publications
The indole scaffold will continue to play a vital part in the future of drug discovery and
agrochemical development. Because of this, the necessity for elegant techniques to enable …

Ruthenium-catalysed σ-activation for remote meta-selective C–H functionalisation

JA Leitch, CG Frost - Chemical Society Reviews, 2017 - pubs.rsc.org
Ruthenium-catalysed σ-activation for remote meta -selective C–H functionalisation - Chemical
Society Reviews (RSC Publishing) DOI:10.1039/C7CS00496F Royal Society of Chemistry …

Chiral transient directing groups in transition-metal-catalyzed enantioselective C–H bond functionalization

MI Lapuh, S Mazeh, T Besset - ACS Catalysis, 2020 - ACS Publications
Transition-metal-catalyzed C–H bond functionalization has known a rapid evolution in the
last years, offering modern strategies for reaching high molecular complexity in a step-and …

Access to the meta position of arenes through transition metal catalysed C–H bond functionalisation: a focus on metals other than palladium

MT Mihai, GR Genov, RJ Phipps - Chemical Society Reviews, 2018 - pubs.rsc.org
The elaboration of simple arenes in order to access more complex substitution patterns is a
crucial endeavor for synthetic chemists, given the central role that aromatic rings play in all …

Palladium (II)‐Initiated Catellani‐Type Reactions

HG Cheng, S Chen, R Chen, Q Zhou - Angewandte Chemie, 2019 - Wiley Online Library
The Catellani reaction is known as a powerful strategy for the expeditious synthesis of highly
substituted arenes and benzo‐fused rings, which are usually difficult to access through …

Visible‐Light‐Enabled Ruthenium‐Catalyzed meta‐C−H Alkylation at Room Temperature

P Gandeepan, J Koeller, K Korvorapun… - Angewandte Chemie …, 2019 - Wiley Online Library
Visible‐light‐induced ruthenium catalysis has enabled remote C− H alkylations with
excellent levels of position control under exceedingly mild conditions at room temperature …