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The medicinal chemist's toolbox for late stage functionalization of drug-like molecules
The advent of modern C–H functionalization chemistries has enabled medicinal chemists to
consider a synthetic strategy, late stage functionalization (LSF), which utilizes the C–H …
consider a synthetic strategy, late stage functionalization (LSF), which utilizes the C–H …
Enantioselective and enantiospecific transition-metal-catalyzed cross-coupling reactions of organometallic reagents to construct C–C bonds
The stereocontrolled construction of C− C bonds remains one of the foremost challenges in
organic synthesis. At the heart of any chemical synthesis of a natural product or designed …
organic synthesis. At the heart of any chemical synthesis of a natural product or designed …
Transition-metal-catalyzed direct addition of unactivated C–H bonds to polar unsaturated bonds
L Yang, H Huang - Chemical Reviews, 2015 - ACS Publications
Transition-metal-catalyzed nucleophilic addition of organometallic reagents to polar
unsaturated substrates is one of the most important and powerful bond-forming strategies …
unsaturated substrates is one of the most important and powerful bond-forming strategies …
Bond formations between two nucleophiles: transition metal catalyzed oxidative cross-coupling reactions
In chemistry, a nucleophile is a molecule or ion with a lone pair of electrons. It donates both
bonding electrons to its reaction partner (the electrophile) when forming a chemical bond. 1 …
bonding electrons to its reaction partner (the electrophile) when forming a chemical bond. 1 …
Efficient, selective, and recyclable palladium catalysts in carbon− carbon coupling reactions
Carbon-carbon cross-coupling reactions are among the most useful and most widely studied
synthetic transformations. The three most important processes, the Heck reaction, the Suzuki …
synthetic transformations. The three most important processes, the Heck reaction, the Suzuki …
Recent advances of transition-metal catalyzed radical oxidative cross-couplings
Conspectus Oxidative cross-coupling reactions between two nucleophiles are a powerful
synthetic strategy to synthesize various kinds of functional molecules. Along with the …
synthetic strategy to synthesize various kinds of functional molecules. Along with the …
Intermolecular dehydrogenative Heck reactions
The Pd-catalyzed reaction of an aryl halide with an alkene affords, in most cases, the
corresponding arylalkene. It is usually considered that this reaction, which is called the Heck …
corresponding arylalkene. It is usually considered that this reaction, which is called the Heck …
[HTML][HTML] Heck reaction—state of the art
S Jagtap - Catalysts, 2017 - mdpi.com
The Heck reaction is one of the most studied coupling reactions and is recognized with the
Nobel Prize in Chemistry. Thousands of articles, hundreds of reviews and a number of …
Nobel Prize in Chemistry. Thousands of articles, hundreds of reviews and a number of …
Expedient Synthesis of N-Acyl Anthranilamides and β-Enamine Amides by the Rh(III)-Catalyzed Amidation of Aryl and Vinyl C–H Bonds with Isocyanates
Expedient Synthesis of N-Acyl Anthranilamides and β-Enamine Amides by the Rh(III)-Catalyzed
Amidation of Aryl and Vinyl C–H Bonds with Isocyanates | Journal of the American Chemical …
Amidation of Aryl and Vinyl C–H Bonds with Isocyanates | Journal of the American Chemical …
Rhodium (III)-catalyzed arylation of boc-imines via C− H bond functionalization
The first rhodium-catalyzed arylation of imines proceeding via C− H bond functionalization is
reported. Use of a non-coordinating halide abstractor is important to obtain reactivity. Aryl …
reported. Use of a non-coordinating halide abstractor is important to obtain reactivity. Aryl …