Site-predictable and chemoselective C–H bond functionalization reactions offer synthetically
powerful strategies for the step-economic diversification of both feedstock and fine …

A critically important process in catalysis is the formation of an active catalyst from the
combination of a metal precursor and a ligand, as the efficacy of this reaction governs the …

Use of a directing group in C–H functionalizations, often referred to as chelation assistance,
is one of the most reliable methods for achieving highly efficient and highly site-selective …

Nickel‐catalyzed electrochemical C− H aminations were accomplished by chemo‐and
position‐selective C− H activation with ample scope. Detailed mechanistic studies …

Alkylation of arenes is one of the most fundamental transformations in chemical synthesis
and leads to privileged scaffolds in many areas of science. Classical methods for the …

Nickel-catalyzed C–H activation has become a predominant and ubiquitous research area
in organic chemistry. Direct functionalization of inert C–H bonds to create functionally …

During the last two decades, impressive advancements have been achieved in transition
metal‐catalyzed chelation‐assisted C—H functionalization reaction. While reactions in this …

The Rh (III)-catalyzed C–H oxidative alkylation of aniline derivatives with readily available
secondary allyl alcohols using a pyrimidine-directing group, leading to the production of β …

Direct alkylations of carboxylic acid derivatives are challenging and particularly nickel
catalysis commonly requires high reaction temperatures and strong bases, translating into …

A unified strategy for nickel (0)‐catalyzed C− H allylations, alkenylations, and dienylations
has been realized through versatile hydroarylations of allenes with ample scope. Thus, an …