Reactivity of surface species in heterogeneous catalysts probed by in situ X-ray absorption techniques

S Bordiga, E Groppo, G Agostini… - Chemical …, 2013 - ACS Publications
Starting from the late seventies, the progressively increased availability of synchrotron light
sources allowed the execution of experiments requiring a high X-ray flux in a continuous …

Probing the surfaces of heterogeneous catalysts by in situ IR spectroscopy

C Lamberti, A Zecchina, E Groppo… - Chemical Society …, 2010 - pubs.rsc.org
This critical review describes the reactivity of heterogeneous catalysts from the point of view
of four simple, but essential for Chemistry, molecules (namely dihydrogen, carbon …

[PDF][PDF] EXAFS and XANES analysis of oxides at the nanoscale

A Kuzmin, J Chaboy - IUCrJ, 2014 - journals.iucr.org
Worldwide research activity at the nanoscale is triggering the appearance of new, and
frequently surprising, materials properties in which the increasing importance of surface and …

Tuning the surface metal work function by deposition of ultrathin oxide films: Density functional calculations

L Giordano, F Cinquini, G Pacchioni - Physical Review B—Condensed Matter …, 2006 - APS
Changes in the work function Φ of metal surfaces upon deposition of ultrathin oxide films
have been studied by means of band structure density functional theory calculations. Four …

Materials characterization by synchrotron x-ray microprobes and nanoprobes

L Mino, E Borfecchia, J Segura-Ruiz, C Giannini… - Reviews of Modern …, 2018 - APS
In recent years synchrotron x-ray microprobes and nanoprobes have emerged as key
characterization tools with a remarkable impact for different scientific fields including solid …

Formation of an Artificial Mg2+-Permeable Interphase on Mg Anodes Compatible with Ether and Carbonate Electrolytes

Y Li, P Zuo, R Li, H Huo, Y Ma, C Du… - … Applied Materials & …, 2021 - ACS Publications
Rechargeable Mg-ion batteries typically suffer from either rapid passivation of the Mg anode
or severe corrosion of the current collectors by halogens within the electrolyte, limiting their …

Carbon monoxide MgO from dispersed solids to single crystals: a review and new advances

G Spoto, EN Gribov, G Ricchiardi, A Damin… - Progress in surface …, 2004 - Elsevier
In this review we describe 30 years of research on the surface properties of magnesium
oxide, considered as the model prototype oxide of cubic structure. The surface properties of …

Low-dimensional systems investigated by x-ray absorption spectroscopy: a selection of 2D, 1D and 0D cases

L Mino, G Agostini, E Borfecchia… - Journal of Physics D …, 2013 - iopscience.iop.org
Over the last three decades low-dimensional systems have attracted increasing interest both
from the fundamental and technological points of view due to their unique physical and …

Determination of the electronic and structural configuration of coordination compounds by synchrotron-radiation techniques

C Garino, E Borfecchia, R Gobetto… - Coordination Chemistry …, 2014 - Elsevier
In this review we provide an overview of the potential of synchrotron radiation techniques to
understand the structural and electronic properties of coordination compounds. Besides the …

What Makes Fe-Modified MgAl2O4 an Active Catalyst Support? Insight from X-ray Raman Scattering

A Longo, SA Theofanidis, C Cavallari, NV Srinath… - ACS …, 2020 - ACS Publications
Fe-modified MgAl2O4 makes a surprisingly active catalyst support, likely linked to a
structural effect of the Fe incorporation. Two catalyst supports, MgAl2O4 and MgFeAlO4 …