Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

In the past two decades, transition metal-catalyzed C–H functionalization followed by
annulations with various coupling partners has received much attention in organic synthesis …

Introducing aryl moieties into heterocyclic scaffolds is a key step in the syntheses of natural
products, drugs, and functional materials. Herein, we describe an unprecedented …

Presented herein is a condition-controlled selective synthesis of pyranone-tethered
indazoles or carbazole derivatives via the cascade reactions of N-nitrosoanilines with …

Herein, we report an acid-controlled highly tunable selectivity of Rh (III)-catalyzed [4+ 2] and
[3+ 3] annulations of N-carboxamide indoles with iodonium ylides lead to form synthetically …

Iodonium ylides have attracted considerable attention due to their unique properties and
numerous applications as versatile and sustainable reagents in organic synthesis …

The past decade has witnessed tremendous developments in transition‐metal‐catalyzed C−
H bond activation and subsequent carbene migratory insertion reactions, thus assisting in …

A straightforward approach to synthesise isocoumarins via Rh (III)-catalyzed C–H/C–C bond
activation/annulation cascade of enaminones and iodonium ylides has been explored. The …

The metal-catalyzed successive activation and functionalization of arene/heteroarene is one
of the most fundamental transformations in organic synthesis and leads to privileged …

Highly selective and switchable [4+ 2] annulations of 2-arylindoles with iodonium ylides
were achieved by performing solvent-controlled Rh (III)-catalyzed C–H activations. When …