Vitrimers: permanent organic networks with glass-like fluidity

W Denissen, JM Winne, FE Du Prez - Chemical science, 2016 - pubs.rsc.org
Most covalent adaptable networks give highly interesting properties for material processing
such as resha**, recycling and repairing. Classical thermally reversible chemical cross …

Advancing the logic of chemical synthesis: C− H activation as strategic and tactical disconnections for C− C bond construction

NYS Lam, K Wu, JQ Yu - Angewandte Chemie, 2021 - Wiley Online Library
The design of synthetic routes by retrosynthetic logic is decisively influenced by the
transformations available. Transition‐metal‐catalyzed C− H activation has emerged as a …

Analysis of past and present synthetic methodologies on medicinal chemistry: where have all the new reactions gone? Miniperspective

DG Brown, J Bostrom - Journal of medicinal chemistry, 2016 - ACS Publications
An analysis of chemical reactions used in current medicinal chemistry (2014), three decades
ago (1984), and in natural product total synthesis has been conducted. The analysis …

Large-scale applications of transition metal-catalyzed couplings for the synthesis of pharmaceuticals

J Magano, JR Dunetz - Chemical Reviews, 2011 - ACS Publications
Research in the mid 1960s to early 1970s sparked an evolution in the approach of synthetic
chemists toward the assembly of molecules. Inspired by known Wacker-type processes in …

[BOOK][B] Handbook of Metathesis, Volume 2: Applications in Organic Synthesis

RH Grubbs, DJ O'Leary - 2015 - books.google.com
The second edition of the" go-to" reference in this field is completely updated and features
more than 80% new content, with emphasis on new developments in the field, especially in …

Cellular incorporation of unnatural amino acids and bioorthogonal labeling of proteins

K Lang, JW Chin - Chemical reviews, 2014 - ACS Publications
In the past 15 years, there have been rapid developments in the ability to cotranslationally
incorporate unnatural amino acids into proteins produced in cells, both at defined sites via …

Cascade reactions in total synthesis

KC Nicolaou, DJ Edmonds… - Angewandte Chemie …, 2006 - Wiley Online Library
The design and implementation of cascade reactions is a challenging facet of organic
chemistry, yet one that can impart striking novelty, elegance, and efficiency to synthetic …

Beyond classical sulfone chemistry: metal-and photocatalytic approaches for C–S bond functionalization of sulfones

J Corpas, SH Kim-Lee, P Mauleón… - Chemical Society …, 2022 - pubs.rsc.org
The exceptional versatility of sulfones has been extensively exploited in organic synthesis
across several decades. Since the first demonstration in 2005 that sulfones can participate …

Recent advances in transition-metal-catalyzed functionalization of unstrained carbon–carbon bonds

F Chen, T Wang, N Jiao - Chemical Reviews, 2014 - ACS Publications
The carbon− carbon bond is the most widespread and fundamental bond existing in organic
compounds. The reaction of this kind of bond is almost ubiquitous in live activities and …

Ruthenium-Based Olefin Metathesis Catalysts Bearing N-Heterocyclic Carbene Ligands

C Samojłowicz, M Bieniek, K Grela - Chemical reviews, 2009 - ACS Publications
N-Heterocyclic carbene (NHC) ligands, introduced as analogues to phosphines, are recently
getting wide attention in the design of diverse homogeneous catalytic systems. 1-6 During …