Defective TiOx overlayers catalyze propane dehydrogenation promoted by base metals

S Chen, Y Xu, X Chang, Y Pan, G Sun, X Wang, D Fu… - Science, 2024 - science.org
The industrial catalysts utilized for propane dehydrogenation (PDH) to propylene, an
important alternative to petroleum-based cracking processes, either use expensive metals or …

Critical analysis on catalytic methylcyclohexane dehydrogenation reaction: A review

X Dai, R Verma, X Zhang, J Bai, SK Verma… - International Journal of …, 2024 - Elsevier
The petrochemical, pharmaceutical, and organic industries all depend on the hydrogenation
of aromatic chemicals. Methylcyclohexan has a very high hydrogen capacity (6.22 wt%) and …

Dynamic stable Pt13 clusters anchored on isolated ZnOx nanorafts for efficient cycloparaffin dehydrogenation

M Song, R Zhang, B Zhang, Z Zhai, G Liu - Applied Catalysis B …, 2025 - Elsevier
Methylcyclohexane (MCH) has attracted wide attention as liquid organic hydrogen carriers
for safe alternative and high gravimetric hydrogen density. Pt 13 cluster with its fascinating …

Achieving Photocatalytic Overall Nitrogen Fixation via an Enzymatic Pathway on a Distorted CoP4 Configuration

X Wang, Y Zhao, X Wu, B Zhang, J Tian… - Angewandte …, 2024 - Wiley Online Library
Photocatalytic nitrogen (N2) fixation over semiconductors has always suffered from poor
conversion efficiency owing to weak N2 adsorption and the difficulty of N≡ N triple bond …

Facile and Environmentally Friendly Synthesis of Ga2O3/MFI Catalysts for Propane Dehydrogenation

C Weng, D Song, L Gu, H Huang, J Lu… - ACS Applied Materials …, 2024 - ACS Publications
A GaO x-based catalyst is recognized as a promising catalyst for dehydrogenation of light
alkanes. Conventionally, impregnation and calcination are necessary processes for the …

Generation of Surface Ga-H Hydride and Reactivity toward CO2

Z Feng, Q Wang, P Zhang, G Li, J Wang… - The Journal of …, 2024 - ACS Publications
Hydrogen adsorption on gallium oxide was investigated by in situ infrared (IR) spectroscopy
over a temperature range of 30–450° C. Both hydroxyl groups and Ga-H hydrides with a pair …

Isolated Pt Atoms Stabilized by Ga2O3 Clusters Confined in ZSM-5 for Nonoxidative Activation of Ethane

X Dou, K Li, K Zhang, C Zhu, DM Meira, Y Song, P He… - JACS Au, 2024 - ACS Publications
Selective activation of light alkanes is an essential reaction in the petrochemical industry for
producing commodity chemicals, such as light olefins and aromatics. Because of the much …

Propane dehydrogenation over binuclear Ga-oxo species stabilized by paired Al-Sites in Ga/ZSM-5: A First-Principles investigation

Z Feng, X Liu, C Meng - Applied Surface Science, 2024 - Elsevier
Ga/ZSM-5 is highly efficient for the direct dehydrogenation of propane (PDH) and binuclear
Ga-oxo species were recently proposed to account for the observed PDH performance …

Surface Structure Dependent Activation of Hydrogen over Metal Oxides during Syngas Conversion

B Bai, Y Ye, F Jiao, J **ao, Y Pan, Z Cai… - Journal of the …, 2024 - ACS Publications
Despite the extensive studies on the adsorption and activation of hydrogen over metal
oxides, it remains a challenge to investigate the structure-dependent activation of hydrogen …

Effects of Cofeeding Hydrogen on Propane Dehydrogenation Catalyzed by Isolated Iron Sites Incorporated into Dealuminated BEA

A Alghannam, AT Bell - Journal of the American Chemical Society, 2025 - ACS Publications
Iron sites dispersed on nonacidic siliceous supports have been reported to be catalytically
active for propane dehydrogenation (PDH), yet the precise relationship between site …