50th Anniversary Perspective: RAFT PolymerizationA User Guide

S Perrier - Macromolecules, 2017 - ACS Publications
This Perspective summarizes the features and limitations of reversible addition–
fragmentation chain transfer (RAFT) polymerization, highlighting its strengths and …

Living radical polymerization by the RAFT process–a third update

G Moad, E Rizzardo, SH Thang - Australian Journal of Chemistry, 2012 - CSIRO Publishing
This paper provides a third update to the review of reversible deactivation radical
polymerization (RDRP) achieved with thiocarbonylthio compounds (ZC (= S) SR) by a …

Expanding the scope of RAFT polymerization: recent advances and new horizons

MR Hill, RN Carmean, BS Sumerlin - Macromolecules, 2015 - ACS Publications
Reversible deactivation radical polymerization (RDRP) has revolutionized modern polymer
chemistry over the past two decades, thus laying the groundwork for the synthesis of …

Functional polymers for optoelectronic applications by RAFT polymerization

G Moad, M Chen, M Häussler, A Postma… - Polymer …, 2011 - pubs.rsc.org
This review focuses on the approaches to the synthesis of functional polymers for
optoelectronic applications that make use of radical polymerization with reversible addition …

On the critical role of RAFT agent design in reversible addition-fragmentation chain transfer (RAFT) polymerization

M Destarac - Polymer reviews, 2011 - Taylor & Francis
There are a certain number of precautions a polymer chemist should take before
undertaking a reversible addition-fragmentation chain transfer (RAFT) polymerization with a …

Dithioesters in RAFT polymerization

G Moad - RAFT Polymerization: Methods, Synthesis and …, 2021 - Wiley Online Library
This chapter provides a review of the synthesis, properties, and application of dithioesters
with the general structure Z (C S) SR as reversible addition–fragmentation chain transfer …

Synthesis and Reactivity of Phosphinocarbyne Complexes

AL Colebatch, AF Hill, M Sharma - Organometallics, 2015 - ACS Publications
The successive treatment of [W ( CBr)(CO) 2 (Tp*)](Tp*= hydrotris (3, 5-dimethylpyrazol-1-
yl) borate) with n BuLi and ClPPh2 affords the phosphinocarbyne complex [W ( …

Phosphorus‐Containing Gradient (Block) Copolymers via RAFT Polymerization and Postpolymerization Modification

KJ Sykes, S Harrisson… - … Chemistry and Physics, 2016 - Wiley Online Library
Reversible addition‐fragmentation chain transfer (RAFT) copolymerization of styrene (St)
and 4‐(diphenylphosphino) styrene (DPPS) is explored to establish the statistical …

Chromium and molybdenum pentacarbonyl complexes of phosphinocarbodithioates: synthesis, molecular structure and behaviour in RAFT polymerisation

R Geagea, S Ladeira, S Mazières… - … –A European Journal, 2011 - Wiley Online Library
Molybdenum and chromium pentacarbonyldiphenylphosphinocarbodithi… complexes have
been prepared in a one‐pot reaction from the corresponding …

Phosphinoyl and thiophosphinoylcarbodithioates: synthesis, molecular structure, and application as new efficient mediators for raft polymerization

S Mazières, I Kulai, R Geagea… - … A European Journal, 2015 - Wiley Online Library
New phosphinoyl and thiophosphinoylcarbodithioates were synthesized in a one‐pot
reaction from the corresponding phosphinochalcogenides. Compounds of this new …