Electron transfer catalysis mediated by 3d complexes of redox non-innocent ligands possessing an azo function: a perspective
It was first reported almost two decades ago that ligands with azo functions are capable of
accepting electron (s) upon coordination to produce azo-anion radical complexes, thereby …
accepting electron (s) upon coordination to produce azo-anion radical complexes, thereby …
Multi-hydroxyl POSS supported iridium complexes as a recyclable catalyst for selective synthesis of N-/C-substituted indoles and the total synthesis of HIV-1 fusion …
J Li, L Chen, L Wang, G Shi, D Wang - Journal of Catalysis, 2024 - Elsevier
A novel pyridyl-thiadiazole ligand has been designed, synthesized, and employed in the
preparation of a heterogeneous iridium catalyst supported on multi-hydroxyl polyhedral …
preparation of a heterogeneous iridium catalyst supported on multi-hydroxyl polyhedral …
Divergence in CH alkylation of indoles under Mn catalysis
Achieving divergence in CH alkylation of substrates using feedstock chemicals is an
attractive paradigm to enable the production of diverse products from the same starting …
attractive paradigm to enable the production of diverse products from the same starting …
Dioxygen Controlled Chemodivergent Cross‐Coupling of Primary and Secondary Alcohols Using Noninnocent Azo Aromatic Complexes of Cobalt (II) as Catalysts
Herein, employing pincer like cobalt (II) complexes containing redox noninnocent azo‐
benzimidazole ligand a switchable and chemodivergent catalytic cross‐coupling of primary …
benzimidazole ligand a switchable and chemodivergent catalytic cross‐coupling of primary …
Photochemical dehydrogenative transformation to heterocycles facilitated by an azo/hydrazo redox couple
Despite the rich redox chemistry available for the azo motif, studies on its photochemical
activation and subsequent application in catalysis are scarce. We design a small organic …
activation and subsequent application in catalysis are scarce. We design a small organic …
Well-defined cobalt (ii)-catalyzed synthesis of perimidine derivatives via acceptorless dehydrogenative annulation
The versatility of the perimidine moiety offers a rich playground for researchers in fields
ranging from medical science to industrial chemistry. Herein, we describe the first Co …
ranging from medical science to industrial chemistry. Herein, we describe the first Co …
Ligand Redox Controlled Amine Dehydrogenation and Imine Hemilability in Singlet Diradical Azo-aromatic Ni (II) Complexes: Characterization of the Electron Transfer …
Herein, using azo-amine (H2L) and azo-imine (L1-3) ligands, singlet diradical Ni (II)
complexes [1] and [2] were synthesized from Ni (0)(COD) 2 in THF. In separate reactions …
complexes [1] and [2] were synthesized from Ni (0)(COD) 2 in THF. In separate reactions …
Zn (II)‐Stabilized Azo‐Anion Radical Catalyzed Sustainable C− C Bond Formation: Regioselective Alkylation of Fluorene, Oxindole, and Indoles
Herein we report a sustainable approach for the alkylation of ketones, 9H‐fluorene,
oxindole, and indole using alcohols as the alkylating agent catalyzed by a well‐defined air …
oxindole, and indole using alcohols as the alkylating agent catalyzed by a well‐defined air …
Ruthenium complexes of redox non-innocent aryl-azo-oximes for catalytic α-alkylation of ketones and synthesis of 2-substituted quinolines
S Halder, S Naskar, D Jana, G Kanrar… - New Journal of …, 2024 - pubs.rsc.org
Ruthenium (II) complexes [RuL (CO) Cl (PPh3) 2], 1a–4a, have been synthesized using
ligands PhNNC (Ar) NOH, HL 1–4, respectively, by varying the pendant aryl (Ar) groups. The …
ligands PhNNC (Ar) NOH, HL 1–4, respectively, by varying the pendant aryl (Ar) groups. The …
Porous Cross-Linked Polymer PPBI@ Mn Catalyzed the Selective Synthesis of Bisindolylmethane Derivatives
K Zhang, H Zhu, D Wang, ZC Duan - Catalysis Letters, 2024 - Springer
The quest for highly active and efficient ligands in coordination polymer-based catalytic
applications is paramount. The new porous cross-linked polymer manganese composites …
applications is paramount. The new porous cross-linked polymer manganese composites …