Vibrational spectroscopic map, vibrational spectroscopy, and intermolecular interaction
Vibrational spectroscopy is an essential tool in chemical analyses, biological assays, and
studies of functional materials. Over the past decade, various coherent nonlinear vibrational …
studies of functional materials. Over the past decade, various coherent nonlinear vibrational …
Vibrational probes: From small molecule solvatochromism theory and experiments to applications in complex systems
Conspectus The vibrational frequency of a chosen normal mode is one of the most
accurately measurable spectroscopic properties of molecules in condensed phases …
accurately measurable spectroscopic properties of molecules in condensed phases …
Vibrational stark effects of carbonyl probes applied to reinterpret IR and raman data for enzyme inhibitors in terms of electric fields at the active site
IR and Raman frequency shifts have been reported for numerous probes of enzyme
transition states, leading to diverse interpretations. In the case of the model enzyme …
transition states, leading to diverse interpretations. In the case of the model enzyme …
Vibrational solvatochromism of nitrile infrared probes: Beyond the vibrational Stark dipole approach
Systematic probing of local environments around biopolymers is important for understanding
their functions. Therefore, there has been growing interest in in situ measurements of …
their functions. Therefore, there has been growing interest in in situ measurements of …
[HTML][HTML] Theory of coherent two-dimensional vibrational spectroscopy
Two-dimensional (2D) vibrational spectroscopy has emerged as one of the most important
experimental techniques useful to study the molecular structure and dynamics in condensed …
experimental techniques useful to study the molecular structure and dynamics in condensed …
Frequency changes in terminal alkynes provide strong, sensitive, and solvatochromic Raman probes of biochemical environments
The C≡ C stretching frequencies of terminal alkynes appear in the “clear” window of
vibrational spectra, so they are attractive and increasingly popular as site-specific probes in …
vibrational spectra, so they are attractive and increasingly popular as site-specific probes in …
Solvent-independent anharmonicity for carbonyl oscillators
The physical origins of vibrational frequency shifts have been extensively studied in order to
understand noncovalent intermolecular interactions in the condensed phase. In the case of …
understand noncovalent intermolecular interactions in the condensed phase. In the case of …
Ion aggregation in high salt solutions: Ion network versus ion cluster
The critical aggregation phenomena are ubiquitous in many self-assembling systems. Ions
in high salt solutions could also spontaneously form larger ion aggregates, but their effects …
in high salt solutions could also spontaneously form larger ion aggregates, but their effects …
Experimental two-dimensional infrared spectra of methyl thiocyanate in water and organic solvents
Thiocyanates, nitriles, and azides represent a versatile set of vibrational probes to measure
the structure and dynamics in biological systems. The probes are minimally perturbative, the …
the structure and dynamics in biological systems. The probes are minimally perturbative, the …
The mutual interactions of RNA, counterions and water–quantifying the electrostatics at the phosphate–water interface
The structure and dynamics of polyanionic biomolecules, like RNA, are decisively
determined by their electric interactions with the water molecules and the counterions in the …
determined by their electric interactions with the water molecules and the counterions in the …