Metal sites in zeolites: synthesis, characterization, and catalysis

Q Zhang, S Gao, J Yu - Chemical reviews, 2022 - ACS Publications
Zeolites with ordered microporous systems, distinct framework topologies, good spatial
nanoconfinement effects, and superior (hydro) thermal stability are an ideal scaffold for …

Methane oxidation to methanol

NF Dummer, DJ Willock, Q He, MJ Howard… - Chemical …, 2022 - ACS Publications
The direct transformation of methane to methanol remains a significant challenge for
operation at a larger scale. Central to this challenge is the low reactivity of methane at …

Chemical loo**-based energy transformation via lattice oxygen modulated selective oxidation

Z Sun, CK Russell, KJ Whitty, EG Eddings, J Dai… - Progress in Energy and …, 2023 - Elsevier
Modulating anionic oxygen in metal oxides offers exceptional opportunities for energy
material synthesis via redox loo**; however, several challenges such as overoxidation …

Advances in catalytic applications of zeolite‐supported metal catalysts

Q Sun, N Wang, J Yu - Advanced Materials, 2021 - Wiley Online Library
Zeolites possessing large specific surface areas, ordered micropores, and adjustable
acidity/basicity have emerged as ideal supports to immobilize metal species with small sizes …

Active sites and mechanisms in the direct conversion of methane to methanol using Cu in zeolitic hosts: a critical examination

MA Newton, AJ Knorpp, VL Sushkevich… - Chemical Society …, 2020 - pubs.rsc.org
In this critical review we examine the current state of our knowledge in respect of the nature
of the active sites in copper containing zeolites for the selective conversion of methane to …

Reactivity, selectivity, and stability of zeolite‐based catalysts for methane dehydroaromatization

N Kosinov, EJM Hensen - Advanced Materials, 2020 - Wiley Online Library
Non‐oxidative dehydroaromatization is arguably the most promising process for the direct
upgrading of cheap and abundant methane to liquid hydrocarbons. This reaction has not …

Shale gas revolution: catalytic conversion of C1–C3 light alkanes to value-added chemicals

X Li, C Pei, J Gong - Chem, 2021 - cell.com
Shale gas is the main source and reservoir of natural gas, and contains a small fraction of
ethane and propane. Along with the increasing exploitation scale, shale gas has the …

Solvation and mobilization of copper active sites in zeolites by ammonia: consequences for the catalytic reduction of nitrogen oxides

C Paolucci, JR Di Iorio, WF Schneider… - Accounts of chemical …, 2020 - ACS Publications
Conspectus Copper-exchanged chabazite (Cu-CHA) zeolites are catalysts used in diesel
emissions control for the abatement of nitrogen oxides (NO x) via selective catalytic …

Copper phosphate nanostructures as catalysts for the direct methane oxidation

A Matsuda, T Aihara, S Kiyohara… - ACS Applied Nano …, 2024 - ACS Publications
The development of heterogeneous catalysts for the selective direct transformation of
methane (CH4) remains a challenge because of the difficulty in activating the strong C–H …

Structure of copper sites in zeolites examined by Fourier and wavelet transform analysis of EXAFS

VL Sushkevich, OV Safonova, D Palagin… - Chemical …, 2020 - pubs.rsc.org
Copper-exchanged zeolites are a class of redox-active materials that find application in the
selective catalytic reduction of exhaust gases of diesel vehicles and, more recently, the …