Homogeneously catalyzed electroreduction of carbon dioxide—methods, mechanisms, and catalysts
R Francke, B Schille, M Roemelt - Chemical reviews, 2018 - ACS Publications
The utilization of CO2 via electrochemical reduction constitutes a promising approach
toward production of value-added chemicals or fuels using intermittent renewable energy …
toward production of value-added chemicals or fuels using intermittent renewable energy …
Light-driven heterogeneous reduction of carbon dioxide: photocatalysts and photoelectrodes
Light-Driven Heterogeneous Reduction of Carbon Dioxide: Photocatalysts and Photoelectrodes
| Chemical Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical …
| Chemical Reviews ACS ACS Publications C&EN CAS Find my institution Log In Chemical …
Molecular polypyridine-based metal complexes as catalysts for the reduction of CO 2
Polypyridyl transition metal complexes represent one of the more thoroughly studied classes
of molecular catalysts towards CO2 reduction to date. Initial reports in the 1980s began with …
of molecular catalysts towards CO2 reduction to date. Initial reports in the 1980s began with …
Manganese catalysts with bulky bipyridine ligands for the electrocatalytic reduction of carbon dioxide: eliminating dimerization and altering catalysis
With the goal of improving previously reported Mn bipyridine electrocatalysts in terms of
increased activity and reduced overpotential, a bulky bipyridine ligand, 6, 6′-dimesityl-2 …
increased activity and reduced overpotential, a bulky bipyridine ligand, 6, 6′-dimesityl-2 …
Mechanistic contrasts between manganese and rhenium bipyridine electrocatalysts for the reduction of carbon dioxide
[Re (bpy)(CO) 3]− is a well-established homogeneous electrocatalyst for the reduction of
CO2 to CO. Recently, substitution of the more abundant transition metal Mn for Re yielded a …
CO2 to CO. Recently, substitution of the more abundant transition metal Mn for Re yielded a …
Electrochemical and spectroscopic methods for evaluating molecular electrocatalysts
KJ Lee, N Elgrishi, B Kandemir… - Nature Reviews Chemistry, 2017 - nature.com
Modern energy challenges have amplified interest in transition metal-based molecular
electrocatalysts for fuel-forming reactions. The activity of these homogeneous …
electrocatalysts for fuel-forming reactions. The activity of these homogeneous …
Elucidation of the Selectivity of Proton-Dependent Electrocatalytic CO2 Reduction by fac-Re(bpy)(CO)3Cl
A complete mechanism for the proton-dependent electrocatalytic reduction of CO2 to CO by
fac-Re (bpy)(CO) 3Cl that is consistent with experimental observations has been developed …
fac-Re (bpy)(CO) 3Cl that is consistent with experimental observations has been developed …
Develo** a Mechanistic Understanding of Molecular Electrocatalysts for CO2 Reduction using Infrared Spectroelectrochemistry
The use of infrared spectroelectrochemistry (IR-SEC) as a characterization method for
molecular electrocatalysts allows researchers to identify key intermediates and products …
molecular electrocatalysts allows researchers to identify key intermediates and products …
Time-Resolved IR Spectroscopy Reveals a Mechanism with TiO2 as a Reversible Electron Acceptor in a TiO2–Re Catalyst System for CO2 Photoreduction
Attaching the phosphonated molecular catalyst [ReIBr (bpy)(CO) 3] 0 to the wide-bandgap
semiconductor TiO2 strongly enhances the rate of visible-light-driven reduction of CO2 to …
semiconductor TiO2 strongly enhances the rate of visible-light-driven reduction of CO2 to …
Local Proton Source in Electrocatalytic CO2 Reduction with [Mn(bpy–R)(CO)3Br] Complexes
The electrochemical behavior of fac‐[Mn (pdbpy)(CO) 3Br](pdbpy= 4‐phenyl‐6‐(phenyl‐2, 6‐
diol)‐2, 2′‐bipyridine)(1) in acetonitrile under Ar, and its catalytic performances for CO2 …
diol)‐2, 2′‐bipyridine)(1) in acetonitrile under Ar, and its catalytic performances for CO2 …