Comprehensive Summary C‐Glycosides are critical, naturally occurring products and
medicinal candidates, and extensive efforts have been made to explore efficient approaches …

Conspectus The National Research Council's report in 2012 recognized glycosidic bond
forming (glycosylation) reactions as critical due to the central importance of carbohydrates to …

Despite their importance in life and material sciences, the efficient construction of stereo-
defined glycosides remains a challenge. Studies of carbohydrate functions would be …

Guidelines for O-Glycoside Formation from First Principles | ACS Central Science ACS ACS
Publications C&EN CAS Find my institution Log In ACS Central Science ACS Publications …

In the last decade, major advances have been made in homogeneous gold catalysis.
However, AuI/AuIII catalytic cycle remains much less explored due to the reluctance of AuI to …

Amines are the most pivotal class of organic motifs in pharmaceutical compounds. Here we
provide a blueprint for a general synthesis of amines by catalyst differentiation enabled by …

Catalytic glycosylation is a vital transformation in synthetic carbohydrate chemistry due to its
ability to expediate the large-scale oligosaccharide synthesis for glycobiology studies with …

Highly stereoselective construction of 1, 2-cis-Ara p linkages has been achieved, which
featured a broad range of alcoholic acceptors, including strong nucleophiles and complex …

Highly stereoselective access to β-glycosyl esters was disclosed, employing 1-
hydroxybenzotriazole (HOBt) mediated esterification of glycosyl hemiacetals in the presence …

The accessibility to long, branched and complex glycans containing many 1, 2-cis glycosidic
linkages with precise structures remains a challenging task in chemical synthesis. Reported …