Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

Mechanochemistry is becoming more widespread as a technique for molecular synthesis
with new mechanochemical reactions being discovered at increasing frequency. Whilst …

Pick your Pd partners: A number of catalytic systems have been developed for palladium‐
catalyzed C H activation/C C bond formation. Recent studies concerning the palladium …

Arylraryl bond formation is one of the most important tools of modern organic synthesis.
These bonds are very often found in natural products such as alkaloids as well as in …

Research in the mid 1960s to early 1970s sparked an evolution in the approach of synthetic
chemists toward the assembly of molecules. Inspired by known Wacker-type processes in …

The cores of many types of polymers, ligands, natural products, and pharmaceuticals
contain biaryl or substituted aromatic structures, and efficient methods of synthesizing these …

Collectively, palladium‐catalyzed coupling reactions represent some of the most powerful
and versatile tools available to synthetic organic chemists. Their widespread popularity …

A wide array of forms of palladium has been utilized as precatalysts for Heck and Suzuki
coupling reactions over the last 15 years. Historically, nearly every form of palladium used …

Many significant products (drugs, materials, optical devices, etc.) commercialized or in the
development phase, possess aromatic carbon-carbon and aromatic carbonnitrogen bonds …

A general aim of transition metal-catalysed organic synthesis is carbon–carbon (C–C) bond
formation. In this respect, the Pd-catalysed Suzuki–Miyaura (SM) coupling reaction 1 is one …