In Situ and Operando X-ray Scattering Methods in Electrochemistry and Electrocatalysis

OM Magnussen, J Drnec, C Qiu, I Martens… - Chemical …, 2024 - ACS Publications
Electrochemical and electrocatalytic processes are of key importance for the transition to a
sustainable energy supply as well as for a wide variety of other technologically relevant …

An ion‐sieving janus separator toward planar electrodeposition for deeply rechargeable Zn‐metal anodes

X Zhang, J Li, K Qi, Y Yang, D Liu, T Wang… - Advanced …, 2022 - Wiley Online Library
The irregular and random electrodeposition of zinc has emerged as a non‐negligible barrier
for deeply rechargeable aqueous zinc (Zn)‐ion batteries (AZIBs), yet traditional texture …

Structure dependency of the atomic-scale mechanisms of platinum electro-oxidation and dissolution

T Fuchs, J Drnec, F Calle-Vallejo, N Stubb… - Nature Catalysis, 2020 - nature.com
Platinum dissolution and restructuring due to surface oxidation are primary degradation
mechanisms that limit the lifetime of platinum-based electrocatalysts for electrochemical …

Operando Identification of the Reversible Skin Layer on Co3O4 as a Three-Dimensional Reaction Zone for Oxygen Evolution

T Wiegmann, I Pacheco, F Reikowski, J Stettner… - ACS …, 2022 - ACS Publications
Co oxides and oxyhydroxides have been studied extensively in the past as promising
electrocatalysts for the oxygen evolution reaction (OER) in neutral to alkaline media. Earlier …

Colloidal nanocrystals as electrocatalysts with tunable activity and selectivity

YT Guntern, V Okatenko, J Pankhurst, SB Varandili… - Acs …, 2021 - ACS Publications
Correlating the catalyst activity, selectivity, and stability with its structure and composition is
of the utmost importance in advancing the knowledge of heterogeneous electrocatalytic …

[HTML][HTML] Electrochemical oxidation of Pt (111) beyond the place-exchange model

L Jacobse, V Vonk, IT McCrum, C Seitz, MTM Koper… - Electrochimica …, 2022 - Elsevier
Oxide formation plays an important role in the degradation of Pt electrocatalysts. However,
the exact oxide structure and reaction mechanism are not fully understood. Here, we used in …

Structural reorganization of Pt (111) electrodes by electrochemical oxidation and reduction

M Ruge, J Drnec, B Rahn, F Reikowski… - Journal of the …, 2017 - ACS Publications
The surface restructuring of Pt (111) electrodes upon electrochemical oxidation/reduction in
0.1 M HClO4 was studied by in situ grazing-incidence small-angle X-ray scattering and …

Initial stages of Pt (111) electrooxidation: dynamic and structural studies by surface X-ray diffraction

J Drnec, M Ruge, F Reikowski, B Rahn, F Carlà… - Electrochimica …, 2017 - Elsevier
In-situ surface X-ray diffraction is used to characterize the surface oxides on a Pt (111)
surface in 0.1 M HClO 4. Detailed analysis at two potentials confirms that the surface …

In situ X-ray probing reveals fingerprints of surface platinum oxide

D Friebel, DJ Miller, CP O'Grady, T Anniyev… - Physical Chemistry …, 2011 - pubs.rsc.org
In situ X-ray absorption spectroscopy (XAS) at the Pt L3 edge is a useful probe for Pt–O
interactions at polymer electrolyte membrane fuel cell (PEMFC) cathodes. We show that …

Driving force of the initial step in electrochemical Pt (111) oxidation

T Fuchs, V Briega-Martos, JO Fehrs, C Qiu… - The Journal of …, 2023 - ACS Publications
The first step of electrochemical surface oxidation is extraction of a metal atom from its lattice
site to a location in a growing oxide. Here we show by fast simultaneous electrochemical …