In Situ and Operando X-ray Scattering Methods in Electrochemistry and Electrocatalysis
Electrochemical and electrocatalytic processes are of key importance for the transition to a
sustainable energy supply as well as for a wide variety of other technologically relevant …
sustainable energy supply as well as for a wide variety of other technologically relevant …
An ion‐sieving janus separator toward planar electrodeposition for deeply rechargeable Zn‐metal anodes
The irregular and random electrodeposition of zinc has emerged as a non‐negligible barrier
for deeply rechargeable aqueous zinc (Zn)‐ion batteries (AZIBs), yet traditional texture …
for deeply rechargeable aqueous zinc (Zn)‐ion batteries (AZIBs), yet traditional texture …
Structure dependency of the atomic-scale mechanisms of platinum electro-oxidation and dissolution
Platinum dissolution and restructuring due to surface oxidation are primary degradation
mechanisms that limit the lifetime of platinum-based electrocatalysts for electrochemical …
mechanisms that limit the lifetime of platinum-based electrocatalysts for electrochemical …
Operando Identification of the Reversible Skin Layer on Co3O4 as a Three-Dimensional Reaction Zone for Oxygen Evolution
T Wiegmann, I Pacheco, F Reikowski, J Stettner… - ACS …, 2022 - ACS Publications
Co oxides and oxyhydroxides have been studied extensively in the past as promising
electrocatalysts for the oxygen evolution reaction (OER) in neutral to alkaline media. Earlier …
electrocatalysts for the oxygen evolution reaction (OER) in neutral to alkaline media. Earlier …
Colloidal nanocrystals as electrocatalysts with tunable activity and selectivity
Correlating the catalyst activity, selectivity, and stability with its structure and composition is
of the utmost importance in advancing the knowledge of heterogeneous electrocatalytic …
of the utmost importance in advancing the knowledge of heterogeneous electrocatalytic …
[HTML][HTML] Electrochemical oxidation of Pt (111) beyond the place-exchange model
Oxide formation plays an important role in the degradation of Pt electrocatalysts. However,
the exact oxide structure and reaction mechanism are not fully understood. Here, we used in …
the exact oxide structure and reaction mechanism are not fully understood. Here, we used in …
Structural reorganization of Pt (111) electrodes by electrochemical oxidation and reduction
M Ruge, J Drnec, B Rahn, F Reikowski… - Journal of the …, 2017 - ACS Publications
The surface restructuring of Pt (111) electrodes upon electrochemical oxidation/reduction in
0.1 M HClO4 was studied by in situ grazing-incidence small-angle X-ray scattering and …
0.1 M HClO4 was studied by in situ grazing-incidence small-angle X-ray scattering and …
Initial stages of Pt (111) electrooxidation: dynamic and structural studies by surface X-ray diffraction
J Drnec, M Ruge, F Reikowski, B Rahn, F Carlà… - Electrochimica …, 2017 - Elsevier
In-situ surface X-ray diffraction is used to characterize the surface oxides on a Pt (111)
surface in 0.1 M HClO 4. Detailed analysis at two potentials confirms that the surface …
surface in 0.1 M HClO 4. Detailed analysis at two potentials confirms that the surface …
In situ X-ray probing reveals fingerprints of surface platinum oxide
In situ X-ray absorption spectroscopy (XAS) at the Pt L3 edge is a useful probe for Pt–O
interactions at polymer electrolyte membrane fuel cell (PEMFC) cathodes. We show that …
interactions at polymer electrolyte membrane fuel cell (PEMFC) cathodes. We show that …
Driving force of the initial step in electrochemical Pt (111) oxidation
T Fuchs, V Briega-Martos, JO Fehrs, C Qiu… - The Journal of …, 2023 - ACS Publications
The first step of electrochemical surface oxidation is extraction of a metal atom from its lattice
site to a location in a growing oxide. Here we show by fast simultaneous electrochemical …
site to a location in a growing oxide. Here we show by fast simultaneous electrochemical …