Best‐practice DFT protocols for basic molecular computational chemistry

M Bursch, JM Mewes, A Hansen… - Angewandte Chemie …, 2022 - Wiley Online Library
Nowadays, many chemical investigations are supported by routine calculations of molecular
structures, reaction energies, barrier heights, and spectroscopic properties. The lion's share …

[HTML][HTML] Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time

A Zabala-Lekuona, JM Seco, E Colacio - Coordination Chemistry Reviews, 2021 - Elsevier
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …

Earth-abundant photocatalyst for H2 generation from NH3 with light-emitting diode illumination

Y Yuan, L Zhou, H Robatjazi, JL Bao, J Zhou, A Bayles… - Science, 2022 - science.org
Catalysts based on platinum group metals have been a major focus of the chemical industry
for decades. We show that plasmonic photocatalysis can transform a thermally unreactive …

The OpenMolcas Web: A Community-Driven Approach to Advancing Computational Chemistry

G Li Manni, I Fdez. Galván, A Alavi… - Journal of chemical …, 2023 - ACS Publications
The developments of the open-source OpenMolcas chemistry software environment since
spring 2020 are described, with a focus on novel functionalities accessible in the stable …

Air-stable chiral single-molecule magnets with record anisotropy barrier exceeding 1800 K

Z Zhu, C Zhao, T Feng, X Liu, X Ying, XL Li… - Journal of the …, 2021 - ACS Publications
Design and synthesis of air-stable and easily tailored high-performance single-molecule
magnets (SMMs) are of great significance toward the implementation of SMMs in molecular …

OpenMolcas: From source code to insight

I Fdez. Galván, M Vacher, A Alavi… - Journal of chemical …, 2019 - ACS Publications
In this Article we describe the OpenMolcas environment and invite the computational
chemistry community to collaborate. The open-source project already includes a large …

Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet

FS Guo, BM Day, YC Chen, ML Tong, A Mansikkamäki… - Science, 2018 - science.org
Single-molecule magnets (SMMs) containing only one metal center may represent the lower
size limit for molecule-based magnetic information storage materials. Their current drawback …

[HTML][HTML] Modern quantum chemistry with [Open] Molcas

F Aquilante, J Autschbach, A Baiardi… - The Journal of …, 2020 - pubs.aip.org
MOLCAS/OpenMolcas is an ab initio electronic structure program providing a large set of
computational methods from Hartree–Fock and density functional theory to various …

Non-adiabatic excited-state molecular dynamics: Theory and applications for modeling photophysics in extended molecular materials

TR Nelson, AJ White, JA Bjorgaard, AE Sifain… - Chemical …, 2020 - ACS Publications
Optically active molecular materials, such as organic conjugated polymers and biological
systems, are characterized by strong coupling between electronic and vibrational degrees of …

Recent advances and perspectives on nonadiabatic mixed quantum–classical dynamics

R Crespo-Otero, M Barbatti - Chemical reviews, 2018 - ACS Publications
Nonadiabatic mixed quantum–classical (NA-MQC) dynamics methods form a class of
computational theoretical approaches in quantum chemistry tailored to investigate the time …