One of the determining factors in whether single-molecule magnets (SMMs) may be used as
the smallest component of data storage, is the size of the barrier to reversal of the …

Abstract Single‐ion magnets (SIMs), exhibiting slow magnetization relaxation in the absence
of the magnetic field, originate from their single spin‐carrier centre. In pursuit of high …

Single-molecule magnets (SMMs) that contain one spin centre (so-called single-ion
magnets) theoretically represent the smallest possible unit for spin-based electronic devices …

Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

This review considers the most recent experimental developments in the magnetic
anisotropy of mono-nuclear transition metal complexes in various coordination …

Single-molecule magnets that contain one spin centre may represent the smallest possible
unit for spin-based computational devices. Such applications, however, require the …

This review examines mononuclear metal complexes with high magnetic anisotropy and the
theoretical approaches used to rationalize their magnetic properties. Electronic structure …

The study of how spin interacts with lattice vibrations and relaxes to equilibrium provides
unique insights into its chemical environment and the relation between electronic structure …

Transition metal ions with long-lived spin states represent minimum size magnetic bits.
Magnetic memory has often been associated with the combination of high spin and strong …