Multifunctionality of luminescent molecular nanomagnets based on lanthanide complexes

R Jankowski, M Wyczesany, S Chorazy - Chemical Communications, 2023 - pubs.rsc.org
Multifunctional materials, which exhibit diverse physical properties, are candidates for the
new generation of smart devices that realize many tasks simultaneously. Particular attention …

Strong Ferromagnetic Exchange Coupling and Single-Molecule Magnetism in MoS43-Bridged Dilanthanide Complexes

LE Darago, MD Boshart, BD Nguyen… - Journal of the …, 2021 - ACS Publications
We report the synthesis and characterization of the trinuclear 4d–4f compounds [Co
(C5Me5) 2][(C5Me5) 2Ln (μ-S) 2Mo (μ-S) 2Ln (C5Me5) 2], 1-Ln (Ln= Y, Gd, Tb, Dy) …

Slow magnetic relaxation in a palladium–gadolinium complex induced by electron density donation from the palladium ion

DC Izuogu, T Yoshida, H Zhang… - … A European Journal, 2018 - Wiley Online Library
Incorporating palladium in the first coordination sphere of acetato‐bridged lanthanoid
complexes,[Pd2Ln2 (H2O) 2 (AcO) 10]⋅ 2 AcOH (Ln= Gd (1), Y (2), Gd0. 4Y1. 6 (3), Eu (4)) …

Intermolecular mechanism for multiple maxima in molecular dynamic susceptibility

LTA Ho, LF Chibotaru - Physical Review B, 2018 - APS
A simple two-level system is introduced to demonstrate the existence of the intermolecular
mechanism of the appearance/disappearance of multiple maxima in molecular dynamic …

Periodicity of Single‐Molecule Magnet Behaviour of Heterotetranuclear Lanthanide Complexes across the Lanthanide Series: A Compendium

DC Izuogu, T Yoshida, G Cosquer… - … A European Journal, 2020 - Wiley Online Library
Acetato‐bridged palladium–lanthanide tetranuclear heterometallic complexes of the form
[Pd2Ln2 (H2O) 2 (CH3COO) 10]⋅ 2 CH3COOH [Ln2= Ce2 (1), Pr2 (2), Nd2 (3), Sm2 (4) …

Dual Emission of a Cyclic Hexanuclear Gold(I) Complex. Interplay between Au3 and Au2 Ligand-Supported Luminophores

P Ai, M Mauro, AA Danopoulos… - The Journal of …, 2018 - ACS Publications
Finding diverse and tunable molecular structures is relevant toward the design of functional
nanostructures. The photoluminescence of complex [Au2Cl (μ-PC-κP, κC, κN)] 3 (1) …

Evolution of metal-thiocarboxylate chemistry in 21st century

S Singh - Journal of Molecular Structure, 2021 - Elsevier
Metal-thiocarboxylate complexes have interesting features in coordination chemistry as well
as in material applications along with some role in the biological system. Which are glint by …

Importance of Axial Symmetry in Elucidating Lanthanide–Transition Metal Interactions

NA Bonde, JB Petersen, MA Sørensen… - Inorganic …, 2019 - ACS Publications
In this paper, we experimentally study and model the electron donating character of an axial
diamagnetic Pd2+ ion in four metalloligated lanthanide complexes of formula [PPh4][Ln {Pd …

Experimental assignment of long-range magnetic communication through Pd & Pt metallophilic contacts

EMH Larsen, NA Bonde, H Weihe, J Ollivier… - Chemical …, 2023 - pubs.rsc.org
Record-breaking magnetic exchange interactions have previously been reported for 3d-
metal dimers of the form [M (Pt (SAc) 4)(pyNO2)] 2 (M= Ni or Co) that are linked in the solid …

Probing Optical Anisotropy and Polymorph‐Dependent Photoluminescence in [Ln2] Complexes by Hyperspectral Imaging on Single Crystals

D Errulat, B Gabidullin, M Murugesu… - … –A European Journal, 2018 - Wiley Online Library
Two homodinuclear and one heterodinuclear lanthanide (Ln)‐based complexes of the
general formula [Ln2 (bpm)(tfaa) 6](Ln= Eu (1), Tb (2), Eu− Tb (3), bpm= 2, 2′‐bipyrimidine …