Electron transfer catalysis mediated by 3d complexes of redox non-innocent ligands possessing an azo function: a perspective
It was first reported almost two decades ago that ligands with azo functions are capable of
accepting electron (s) upon coordination to produce azo-anion radical complexes, thereby …
accepting electron (s) upon coordination to produce azo-anion radical complexes, thereby …
Recent advances on the chemistry of transition metal complexes of 2-(arylazo) pyridines and its arylamino derivatives
Recent advancement on the redox properties of a selection of transition metal complexes of
the azoaromatic ligands: bidentate L1 [2-(arylazo) pyridine] and tridentate HL2 [2 …
the azoaromatic ligands: bidentate L1 [2-(arylazo) pyridine] and tridentate HL2 [2 …
Redox noninnocent azo-aromatic pincers and their iron complexes. Isolation, characterization, and catalytic alcohol oxidation
The new redox-noninnocent azoaromatic pincers 2-(arylazo)-1, 10-phenanthroline (L1) and
2, 9-bis (phenyldiazo)-1, 10-phenanthroline (L2) are reported. The ligand L1 is a tridentate …
2, 9-bis (phenyldiazo)-1, 10-phenanthroline (L2) are reported. The ligand L1 is a tridentate …
Assigning ligand redox levels in complexes of 2-aminophenolates: Structural signatures
R Mukherjee - Inorganic Chemistry, 2020 - ACS Publications
The purpose of this Viewpoint is to provide a broad-ranging update of advances in the
coordination chemistry of redox-active (noninnocent) 2-aminophenolates, with emphasis on …
coordination chemistry of redox-active (noninnocent) 2-aminophenolates, with emphasis on …
Deprotonation Induced Ligand Oxidation in a NiII Complex of a Redox Noninnocent N1-(2-Aminophenyl)benzene-1,2-diamine and Its Use in Catalytic Alcohol …
Two nickel (II)-complexes,[NiII (H3L) 2](ClO4) 2 ([1](ClO4) 2) and [NiII (HL) 2](2), containing
the redox-active tridentate ligand N 1-(2-aminophenyl) benzene-1, 2-diamine (H3L) have …
the redox-active tridentate ligand N 1-(2-aminophenyl) benzene-1, 2-diamine (H3L) have …
Redox-Induced Interconversion and Ligand-Centered Hemilability in NiII Complexes of Redox-Noninnocent Azo-Aromatic Pincers
A series of nickel (II) complexes, namely,[NiII (La–c) 2Cl2](1a–c),[NiII (La, b) 3](X) 2 {([2a](X)
2,[2b](X) 2)(X= ClO4, I3)},[NiII (Lc) 2 (OH2) 2](ClO4) 2 ([3](ClO4) 2) and [NiII {(La, b)·–} 2](4a …
2,[2b](X) 2)(X= ClO4, I3)},[NiII (Lc) 2 (OH2) 2](ClO4) 2 ([3](ClO4) 2) and [NiII {(La, b)·–} 2](4a …
Iron-catalyzed/mediated C–N bond formation: competition between substrate amination and ligand amination
Iron catalyzed carbon–nitrogen bond formation reactions of a wide variety of nucleophiles
and aryl halides using well-defined iron-complexes featuring redox noninnocent 2-(arylazo) …
and aryl halides using well-defined iron-complexes featuring redox noninnocent 2-(arylazo) …
The Renaissance of Base Metal Catalysis Enabled by Functional Ligands
M Fritz, S Schneider - The Periodic Table II: Catalytic, Materials, Biological …, 2019 - Springer
The replacement of precious metals by base metals in homogeneous catalysis is of great
interest due to their high natural abundance and generally lower toxicity. However, in many …
interest due to their high natural abundance and generally lower toxicity. However, in many …
Synthesis, characterization, structure and catalytic activity of (NNN) tridentate azo-imine nickel (II), palladium (II) and platinum (II) complexes
The newly designed tridentate ligand, 2, 2′-(bisdiamino) azobenzene, H 2 L, 1 derived
from the oxidative coupling of o-phenylenediamine in presence of NaOH base, upon …
from the oxidative coupling of o-phenylenediamine in presence of NaOH base, upon …
Octacoordinated dioxo-molybdenum complex via formal oxidative addition of molecular oxygen. Studies of chemical reactions between M (CO) 6 (M= Cr, Mo) and 2, 4 …
I Chatterjee, N Saha Chowdhury, P Ghosh… - Inorganic …, 2015 - ACS Publications
Reactions of M (CO) 6 (M= Mo, Cr) and 2 mol of 2, 4-di-tert-butyl-6-(pyridin-2-ylazo)-phenol
ligand (HL) in air yielded [MoVIO2 (L1¯) 2], 1, and [CrIII (L1¯)(L• 2¯)], 2, respectively, in high …
ligand (HL) in air yielded [MoVIO2 (L1¯) 2], 1, and [CrIII (L1¯)(L• 2¯)], 2, respectively, in high …