Metal–organic frameworks as catalysts and biocatalysts for methane oxidation: The current state of the art
As the main component of natural and shale gas, seabed clathrates, and biogas, methane
(CH 4) is an abundant C1 resource for added-value chemicals. CH 4 is of critical importance …
(CH 4) is an abundant C1 resource for added-value chemicals. CH 4 is of critical importance …
Direct Methane Oxidation by Copper-and Iron-Dependent Methane Monooxygenases
FJ Tucci, AC Rosenzweig - Chemical reviews, 2024 - ACS Publications
Methane is a potent greenhouse gas that contributes significantly to climate change and is
primarily regulated in Nature by methanotrophic bacteria, which consume methane gas as …
primarily regulated in Nature by methanotrophic bacteria, which consume methane gas as …
Methane activation by a mononuclear copper active site in the zeolite mordenite: Effect of metal nuclearity on reactivity
The direct conversion of methane to methanol would have a wide reaching environmental
and industrial impact. Copper-containing zeolites can perform this reaction at low …
and industrial impact. Copper-containing zeolites can perform this reaction at low …
Unraveling the valence state and reactivity of copper centers in membrane-bound particulate methane monooxygenase
W Peng, Z Wang, Q Zhang, S Yan… - Journal of the American …, 2023 - ACS Publications
Particulate methane monooxygenase (pMMO) plays a critical role in catalyzing the
conversion of methane to methanol, constituting the initial step in the C1 metabolic pathway …
conversion of methane to methanol, constituting the initial step in the C1 metabolic pathway …
In Situ UV–Vis–NIR Absorption Spectroscopy and Catalysis
This review highlights in situ UV–vis–NIR range absorption spectroscopy in catalysis. A
variety of experimental techniques identifying reaction mechanisms, kinetics, and structural …
variety of experimental techniques identifying reaction mechanisms, kinetics, and structural …
Second-sphere lattice effects in copper and iron zeolite catalysis
Transition-metal-exchanged zeolites perform remarkable chemical reactions from low-
temperature methane to methanol oxidation to selective reduction of NOx pollutants. As with …
temperature methane to methanol oxidation to selective reduction of NOx pollutants. As with …
Transition metal oxide complexes as molecular catalysts for selective methane to methanol transformation: any prospects or time to retire?
Transition metal oxides have been extensively used in the literature for the conversion of
methane to methanol. Despite the progress made over the past decades, no method with …
methane to methanol. Despite the progress made over the past decades, no method with …
A Reactive, Photogenerated High-Spin (S = 2) FeIV(O) Complex via O2 Activation
Addition of dioxygen at low temperature to the non-heme ferrous complex FeII
(Me3TACN)((OSiPh2) 2O)(1) in 2-MeTHF produces a peroxo-bridged diferric complex Fe2III …
(Me3TACN)((OSiPh2) 2O)(1) in 2-MeTHF produces a peroxo-bridged diferric complex Fe2III …
106-fold faster C–H bond hydroxylation by a CoIII,IV2(µ-O)2 complex [via a CoIII2(µ-O)(µ-OH) intermediate] versus its FeIIIFeIV analog
Y Li, C Abelson, L Que Jr… - Proceedings of the …, 2023 - National Acad Sciences
The hydroxylation of C–H bonds can be carried out by the high-valent CoIII, IV2 (µ-O) 2
complex 2a supported by the tetradentate tris (2-pyridylmethyl) amine ligand via a CoIII2 (µ …
complex 2a supported by the tetradentate tris (2-pyridylmethyl) amine ligand via a CoIII2 (µ …
Direct and remote control of electronic structures and redox potentials in μ-oxo diferric complexes
S Finke, A Stammler, J Oldengott, S Walleck… - Dalton …, 2023 - pubs.rsc.org
Non-heme diiron enzymes activate O2 for the oxidation of substrates in the form of peroxo
FeIII2 or high-valent FeIV2 intermediates. We have developed a dinucleating bis …
FeIII2 or high-valent FeIV2 intermediates. We have developed a dinucleating bis …