Circularly Polarized Luminescent π‐Conjugated Chiral Nanorings and Nanobelts

Y Xue, Y Shi, P Chen - Advanced Optical Materials, 2024 - Wiley Online Library
Molecular chirality plays a pivotal role across the disciplines of chemical and physical
sciences, as well as holding significant implications in the realms of medicine and …

Aqueous circularly polarized luminescence induced by homopolypeptide self-assembly

J Jiang, F Ma, R Dong, S Zhang, Z Zhang… - Journal of the …, 2023 - ACS Publications
Remarkable advances have been achieved in solution self-assembly of polypeptides from
the perspective of nanostructures, mechanisms, and applications. Despite the intrinsic …

Magnetic Circularly Polarized Luminescence of Organic Compounds

F Zinna, G Pescitelli - European Journal of Organic Chemistry, 2023 - Wiley Online Library
Achiral purely organic molecules can show selectivity towards circularly polarized light in
emission in the presence of a magnetic field. This phenomenon is called magnetic circularly …

Triple para-Functionalized Cations and Neutral Radicals of Enantiopure Diaza[4]helicenes

B Fabri, T Funaioli, L Frédéric, C Elsner… - Journal of the …, 2024 - ACS Publications
Modulation of absorbance and emission is key for the design of chiral chromophores.
Accessing a series of compounds absorbing and emitting (circularly polarized) light over a …

Synthesis of Aza[n]helicenes up to n = 19: Hydrogen-Bond-Assisted Solubility and Benzannulation Strategy

Y Matsuo, M Gon, K Tanaka, S Seki… - Journal of the American …, 2024 - ACS Publications
Synthetic challenges toward anomalous structures and electronic states often involve
handling problems such as insolubility in common organic solvents and oxidative …

Enantioselective synthesis of a two-fold inherently chiral molecular nanographene

M Buendía, JM Fernández-García, J Perles… - Nature …, 2024 - nature.com
The introduction and precise control of stereogenic elements in chemical structures is
typically a challenging task. Most asymmetric methods require the presence of a heteroatom …

Benzo-extended heli (aminoborane) s: Inner rim BN-doped helical molecular carbons with remarkable chiroptical properties

Y Yu, C Wang, FF Hung, C Chen, D Pan… - Journal of the …, 2024 - ACS Publications
Atomically precise synthesis of three-dimensional boron–nitrogen (BN)-based helical
structures constitutes an undeveloped field with challenges in synthetic chemistry. Herein …

Red Emissive Double Aza [7] helicenes with Antiaromaticity/Aromaticity Switching via the Redox‐Induced Radical Cation and Dication Species

C Li, C Zhang, P Li, Y Jia, J Duan, M Liu… - Angewandte Chemie …, 2023 - Wiley Online Library
We herein present the synthetic approach to a new antiaromatic double aza [7] helicene C
that features NN‐embedded polycyclic aromatic hydrocarbons (PAHs). This heteroatom …

Boosting quantum yields and circularly polarized luminescence of penta-and hexahelicenes by do** with two BN-groups

Y Appiarius, S Míguez-Lago, P Puylaert, N Wolf… - Chemical …, 2024 - pubs.rsc.org
The incorporation of boron–nitrogen (BN) units into polycyclic aromatic hydrocarbons
(PAHs) as an isoelectronic replacement of two carbon atoms can significantly improve their …

Hierarchical chiral MOFs with the induced chirality of AIE ligands exhibiting non-reciprocal CPL

HR Fu, DD Ren, K Zhang, S Wang, XJ Yang… - Chemical …, 2024 - pubs.rsc.org
Two pairs of chiral MOFs with hierarchical chiral structures were constructed through
assembly of achiral AIE-type multidentate linkers and chiral camphoric acid. Non-reciprocal …