Optical phenomena in molecule-based magnetic materials

JJ Zakrzewski, M Liberka, J Wang, S Chorazy… - Chemical …, 2024 - ACS Publications
Since the last century, we have witnessed the development of molecular magnetism which
deals with magnetic materials based on molecular species, ie, organic radicals and metal …

Domain wall dynamics in a ferroelastic spin crossover complex with giant magnetoelectric coupling

VB Jakobsen, E Trzop, E Dobbelaar… - Journal of the …, 2021 - ACS Publications
Pinned and mobile ferroelastic domain walls are detected in response to mechanical stress
in a Mn3+ complex with two-step thermal switching between the spin triplet and spin quintet …

Facile synthesis of Mn-Ni bimetal organic framework decorated with amine as an electrode for a high-performance supercapacitor

S Rajasekaran, BS Reghunath, SD KR… - Journal of Solid State …, 2023 - Springer
In the recent years, the whole world is looking for better energy storage devices.
Supercapacitors are among the most promising high-capacity energy storage devices …

Spin-state switching: chemical modulation and the impact of intermolecular interactions in manganese (iii) complexes

S Bagchi, S Kamilya, S Mehta, S Mandal… - Dalton …, 2023 - pubs.rsc.org
A series of mononuclear manganese (III) complexes [Mn (X-sal2-323)](ReO4)(X= 5 Cl, 1; X=
5 Br, 2; X= 3, 5 Cl, 3; X= 3, 5 Br, 4; and X= 5 NO2, 5), containing hexadentate ligands …

The dynamic interplay between intramolecular and intermolecular interactions in mononuclear manganese (III) SCO complexes

CY Qin, SZ Zhao, HY Wu, YH Li, ZK Wang… - Dalton …, 2021 - pubs.rsc.org
The effect of counter anions on thermally induced manganese (III)-based SCO within the [Mn
(5-F-sal-N-1, 5, 8, 12)] Y family has been investigated. All the complexes are crystallized …

Compressed and Expanded Lattices - Barriers to Spin-State Switching in Mn3+ Complexes

MM Harris, IA Kühne, CT Kelly… - Crystal Growth & …, 2023 - ACS Publications
We report the structural and magnetic properties of two new Mn3+ complex cations in the
spin crossover (SCO)[Mn (R-sal2323)]+ series, in lattices with seven different counterions in …

The cooperative effects of ligand substituent positions and solvents on spin crossover in Mn (III) complexes based on hexadentate Schiff-base ligands

HZ Zhang, HW Zhou, PY Xu, CY Qin, SZ Zhao, YH Li… - Polyhedron, 2024 - Elsevier
Spin crossover (SCO), as a molecular bistable phenomenon, has attracted extensive
interest. In this paper, the syntheses, crystal structures and magnetic properties of three Mn …

Impact of counter anions on spin-state switching of manganese (III) complexes containing an azobenzene ligand

S Ghosh, S Bagchi, S Kamilya, S Mehta, D Sarkar… - Dalton …, 2022 - pubs.rsc.org
Four mononuclear manganese (III) complexes coordinated with photo-active hexadentate
azobenzene ligands,[Mn (5azo-sal2-323)](X)(X= Cl, 1; X= BF4, 2; X= ClO4, 3; X= PF6, 4) …

Solvation of Manganese (III) Ion in Water and in Ammonia

A Malloum, J Conradie - The Journal of Physical Chemistry A, 2023 - ACS Publications
In this work, we have studied the solvation of manganese (III) ion in water and in ammonia
using three levels of theory: MP2, MN15, and ωB97XD associated with the aug-cc-pVDZ …

The effect of fluorine substituents on the crystal structure and spin crossover behavior of the cation [Mn III (3, 5-diHal-sal 2 323)]+ complex family with BPh 4 anions

AV Tiunova, AV Kazakova, DV Korchagin… - New Journal of …, 2022 - pubs.rsc.org
Mononuclear Mn (III) cation spin-crossover complexes with Schiff base ligands 3, 5-diF-
sal2323 and 3, 5-Br, F-sal2323 have been synthesized:[Mn (3, 5-diF-sal2323)] BPh4 (1) and …