Copper in cross-coupling reactions: The post-Ullmann chemistry

IP Beletskaya, AV Cheprakov - Coordination Chemistry Reviews, 2004 - Elsevier
In the last decade, a number of methods using various copper complexes and salts to carry
out cross-coupling reactions leading to the formation of Cheteroatom (CN, CO, CS, CP …

Benzocyclotrimers: from the Mills− Nixon effect to gas hosting

F Fabris, C Zonta, G Borsato… - Accounts of Chemical …, 2011 - ACS Publications
The formal annulation of three bicylic olefins yields a class of molecules termed
benzocyclotrimers (BCTs), which have unusual electronic properties. The bonds in the …

2, 3, 6, 7, 10, 11‐Hexamethoxytribenzotriquinacene: Synthesis, Solid‐State Structure, and Functionalization of a Rigid Analogue of Cyclotriveratrylene

M Harig, B Neumann, HG Stammler… - European Journal of …, 2004 - Wiley Online Library
The syntheses of several tribenzotriquinacenes bearing six methoxy groups at the outer
peripheral positions of the aromatic rings are reported. The centro‐methyl derivative is …

Stereoselective Cyclotrimerization of Enantiopure Iodonorbornenes Catalyzed by Pd Nanoclusters for C3 or C3v Symmetric syn-Tris(norborneno)benzenes

S Higashibayashi, AFG Masud Reza… - The Journal of Organic …, 2010 - ACS Publications
C 3 or C 3 v symmetric enantiopure syn-tris (norborneno) benzenes with various functional
groups were synthesized through Pd-catalyzed cyclotrimerization of enantiopure …

Molecular encapsulation via metal-to-ligand coordination in a Cu (I)-folded molecular basket

S Rieth, Z Yan, S **a, M Gardlik, A Chow… - The Journal of …, 2008 - ACS Publications
A molecular basket, composed of a semirigid C 3 v symmetric tris-norbornadiene framework
and three pyridine flaps at the rim, has been shown to coordinate to a Cu (I) cation and …

Supramolecular catalysis at work: Diastereoselective synthesis of a molecular bowl with dynamic inner space

Z Yan, T McCracken, S **a, V Maslak… - The Journal of …, 2008 - ACS Publications
The supramolecular assistance to Pd (0)/Cu (I)-catalyzed cyclotrimerization of stannylated
norbornene 7 has been investigated to give molecular bowl 1 syn in a stereoselective …

Synthesis of an Enantiopure syn-Benzocyclotrimer through Regio-selective Cyclotrimerization of a Halonorbornene Derivative under Palladium Nanocluster …

S Higashibayashi, H Sakurai - Chemistry letters, 2007 - academic.oup.com
An enantiopure syn-benzocyclotrimer 1 was selectively synthesized from an enantiopure
halonorbornene 2 through regio-selective cyclotrimerization catalyzed by palladium …

Preparation of C3‐Symmetric Homochiral syn‐Trisnorbornabenzenes through Regioselective Cyclotrimerization of Enantiopure Iodonorbornenes

AFGM Reza, S Higashibayashi… - Chemistry–An Asian …, 2009 - Wiley Online Library
Abstract C3‐symmetric homochiral (−)‐syn‐trisoxonorbornabenzene 1 possessing a rigid
cup‐shaped structure was synthesized through a novel regioselective cyclotrimerization of …

(+)-syn-Benzotriborneol: the first functionalised enantiopure C3-symmetric benzocyclotrimer

F Fabris, L Bellotto, O De Lucchi - Tetrahedron letters, 2003 - Elsevier
Copper (I) thiophencarboxylate readily and effectively cyclotrimerises protected 5-bromo-6-
trimethylstannylborn-5-en-2-ols, leading to oxygen-functionalised benzocyclotrimers. The …

Method for the preparation of derivatives of heptiptycene: toward dual-cavity baskets

K Hermann, S Sardini, Y Ruan, RJ Yoder… - The Journal of …, 2013 - ACS Publications
We have developed a novel synthetic method that enables the preparation of functional
derivatives of heptiptycene, ie, cavitands with two juxtaposed cavities. The homocoupling of …