Reactivity Profile of a Formally Dicobalt (0) Complex Bound by a Redox-Active Macrocycle

AZ Spentzos, SA Ford, B Muldowney, T Liu… - …, 2024 - ACS Publications
In this article, we discuss the synthesis, characterization, and reactivity of a neutral dicobalt
complex,[Co 2 (PMe 3) 2] 0, supported by a highly reduced, redox-active macrocyclic ligand …

Controlling the Size of Molecular Copper Clusters Supported by a Multinucleating Macrocycle

Q Wang, RP Murphy, MR Gau, PJ Carroll… - Inorganic …, 2024 - ACS Publications
The use of a nonrigid, pyridyldialdimine-derived macrocyclic ligand (3PDAI2) enabled the
synthesis of well-defined mono-, di-, tri-, and tetra-nuclear Cu (I) complexes in good yields …

Influence of Metal Identity and Complex Nuclearity in Kumada Cross-Coupling Polymerizations with a Pyridine Diimine-Based Ligand Scaffold

AJ King, J Wang, T Liu, A Raghavan… - ACS Polymers …, 2023 - ACS Publications
Cross-coupling polymerizations have fundamentally changed the field of conjugated
polymers (CPs) by expanding the scope of accessible materials. Despite the prevalence of …

Binuclear Complexes Supported by a Tetrapyridyl Ligand with a Bending Anthraquinodimethane Linker

T Iwamoto, Y Sotome, Y Ishii - ACS Organic & Inorganic Au, 2023 - ACS Publications
A tetrapyridyl ligand with a bending anthraquinodimethane linker has been synthesized, and
its complexation with coinage metals has been examined. The treatment of the ligand with …

Role of a redox-active ligand close to a dinuclear activating framework

C Elleouet, FY Pétillon, P Schollhammer - Modes of Cooperative Effects in …, 2022 - Springer
The main advances, over the last two decades, on dinuclear complexes featuring a redox-
active ligand close to the bimetallic core are presented in this chapter. At the end of the …

Dinuclear Reactivity Between the Two Metal Centers

L Maron, P Kalck - Modes of Cooperative Effects in Dinuclear Complexes, 2023 - Springer
In the field of metal-mediated selective and easier organic reactions, the present chapter
focuses on the activation of at least one main step in the cleft of a dinuclear platform, in …

Synthesis and Reactivity Studies Towards Small Molecule Activation of Pyridyldiimine-Derived Macrocyclic Diiron Complexes

T Liu - 2023 - search.proquest.com
Multinuclear metallic cluster complexes have drawn lots of research interests given their
promise in drawing analogies to surface species and metalloenzyme sites. In particular …