This review covers diastereo-and enantiodivergent catalyzed reactions in acyclic and cyclic
systems using metal complexes or organocatalysts. Among them, nucleophilic addition to …

The metal‐catalysed hydrofunctionalisation of alkenes and alkynes provides a convenient
and atom‐economic route to diversely functionalised products with control of regio‐, chemo …

The demand for economical and environmentally benign catalysts for important chemical
transformations has recently initiated great efforts on nonprecious metal-catalyzed …

Catalytic sequential hydrosilylation of 1, 3-enynes and 1, 4-enynes promoted by cobalt
complexes derived from bisphosphines are presented. Site-and stereoselective Si–H …

A bis (imino) pyridine cobalt-catalyzed hydroboration of terminal alkynes with HBPin (Pin=
pinacolate) with high yield and (Z)-selectivity for synthetically valuable vinylboronate esters …

Hydrosilation reactions represent an important class of chemical transformations and there
has been considerable recent interest in expanding the scope of these reactions by …

Hydroboration of alkynes is a practical route for the syntheses of 1-alkenylboron compounds
which are a versatile reagent for organic synthesis. 1, 2 Although much attention has been …

The complex [Cp* Ru (MeCN) 3] PF6 is shown to catalyze the hydrosilylation of a wide
range of alkynes. Terminal alkynes afford access to α-vinylsilane products with good …

A three-coordinate cobalt (I) complex exhibits high catalytic efficiency and selectivity as well
as good functional group compatibility in alkyne hydrosilylation.[Co (IAd)(PPh3)(CH2TMS)] …

Publisher Summary This chapter discusses about compounds or complexes that facilitate
hydrosilation. The word ''true catalyst''is used where the actual catalytic species is positively …