Transition-metal-catalyzed C–S, C–Se, and C–Te bond formations via cross-coupling and atom-economic addition reactions. Achievements and challenges

IP Beletskaya, VP Ananikov - Chemical Reviews, 2022 - ACS Publications
In the present review, we discuss recent progress in the field of C–Z bond formation
reactions (Z= S, Se, Te) catalyzed by transition metals. Two complementary methodologies …

Decarboxylative reactions with and without light–a comparison

J Schwarz, B König - Green Chemistry, 2018 - pubs.rsc.org
Carboxylic acids have gained more and more importance as versatile and renewable
starting materials for the formation of platform molecules or high-value chemicals. Many …

Recent advances in the catalytic synthesis of arylsulfonyl compounds

D Joseph, MA Idris, J Chen, S Lee - ACS Catalysis, 2021 - ACS Publications
Arylsulfonyl compounds are among the most important compounds in pharmaceutical and
medicinal chemistry. Hence, a wide variety of sulfonylation methods have been reported …

Generation of Sulfonyl Radicals from Aryldiazonium Tetrafluoroborates and Sulfur Dioxide: The Synthesis of 3‐Sulfonated Coumarins

D Zheng, J Yu, J Wu - Angewandte Chemie International …, 2016 - Wiley Online Library
A catalyst‐free approach for the generation of sulfonyl radicals from aryldiazonium
tetrafluoroborates in the presence of DABCO⋅(SO2) 2 is realized. The combination of …

Inorganic sulfites as the sulfur dioxide surrogates in sulfonylation reactions

S Ye, G Qiu, J Wu - Chemical Communications, 2019 - pubs.rsc.org
Recent advances in the sulfonylation reactions by using inorganic sulfites as the source of
sulfonyl group are reported. The approaches employing inorganic sulfites as sulfur dioxide …

1, 2‐Difunctionalization of Acetylene Enabled by Light

S Lü, Z Wang, X Gao, K Chen… - Angewandte Chemie …, 2023 - Wiley Online Library
Although the direct conversion of gaseous acetylene into value‐added liquid commodity
chemicals is becoming increasingly attractive, the majority of the established methodologies …

Recent advances in the synthesis of vinyl sulfones

Y Fang, Z Luo, X Xu - RSC advances, 2016 - pubs.rsc.org
Development of the methodology for the preparation of vinyl sulfones is of significant interest
to organic chemists. Recently, numerous useful methods have been developed, mainly …

Sulfonyl hydrazides in organic synthesis: a review of recent studies

S Zhao, K Chen, L Zhang, W Yang… - Advanced Synthesis & …, 2020 - Wiley Online Library
Sulfonyl hydrazides are widely used as organic reagents. Advances in the past decade are
summarized in the following categories by key intermediates:(1)[RO2S.];(2) …

Oxidative Sulfonylation of Multiple Carbon‐Carbon bonds with Sulfonyl Hydrazides, Sulfinic Acids and their Salts

OM Mulina, AI Ilovaisky, VD Parshin… - … Synthesis & Catalysis, 2020 - Wiley Online Library
Oxidative coupling methodology is widely applied for the formation of carbon‐carbon and
carbon‐heteroatom bonds. This review focuses on methods for oxidative sulfonylation of …

Multicomponent hydrosulfonylation of alkynes for the synthesis of vinyl sulfones

L Mei, XR Shu, FL Liu, JZ Li, JF Zhang, K Tang… - Green …, 2023 - pubs.rsc.org
Vinyl sulfones are important structural motifs with a wide range of applications in the
biomedical field. Although the hydrosulfonylations of alkynes have provided straightforward …