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Spontaneous oxidation in aqueous microdroplets: water radical cation as primary oxidizing agent
Exploration of the unique chemical properties of interfaces can unlock new understanding. A
striking example is the finding of accelerated reactions, particularly spontaneous oxidation …
striking example is the finding of accelerated reactions, particularly spontaneous oxidation …
Chemical kinetics in microdroplets
Micrometer-sized compartments play significant roles in driving heterogeneous
transformations within atmospheric and biochemical systems as well as providing vehicles …
transformations within atmospheric and biochemical systems as well as providing vehicles …
Evaluation of AlphaFold-Multimer prediction on multi-chain protein complexes
Motivation Despite near-experimental accuracy on single-chain predictions, there is still
scope for improvement among multimeric predictions. Methods like AlphaFold-Multimer and …
scope for improvement among multimeric predictions. Methods like AlphaFold-Multimer and …
Water–solid contact electrification causes hydrogen peroxide production from hydroxyl radical recombination in sprayed microdroplets
Contact electrification between water and a solid surface is crucial for physicochemical
processes at water–solid interfaces. However, the nature of the involved processes remains …
processes at water–solid interfaces. However, the nature of the involved processes remains …
Sprayed water microdroplets are able to generate hydrogen peroxide spontaneously
Ultrapure N2 gas was bubbled through water, and the humidified output containing
undetectable concentrations of ozone filled a closed chamber in which 18 MΩ-cm water was …
undetectable concentrations of ozone filled a closed chamber in which 18 MΩ-cm water was …
The role of charge in microdroplet redox chemistry
In charged water microdroplets, which occur in nature or in the lab upon ultrasonication or in
electrospray processes, the thermodynamics for reactive chemistry can be dramatically …
electrospray processes, the thermodynamics for reactive chemistry can be dramatically …
Electrostatics and chemical reactivity at the air–water interface
MTC Martins-Costa, MF Ruiz-López - Journal of the American …, 2023 - ACS Publications
It has been recently discovered that chemical reactions at aqueous interfaces can be orders
of magnitude faster compared to conventional bulk phase reactions, but despite its wide …
of magnitude faster compared to conventional bulk phase reactions, but despite its wide …
Spontaneous dark formation of OH radicals at the interface of aqueous atmospheric droplets
Hydroxyl radical (OH) is a key oxidant that triggers atmospheric oxidation chemistry in both
gas and aqueous phases. The current understanding of its aqueous sources is mainly …
gas and aqueous phases. The current understanding of its aqueous sources is mainly …
Spontaneous reduction-induced degradation of viologen compounds in water microdroplets and its inhibition by host–guest complexation
C Gong, D Li, X Li, D Zhang, D **ng… - Journal of the …, 2022 - ACS Publications
Water serves as an inert environment for the dispersion and application of many kinds of
herbicides. Viologen compounds, a type of widely used but highly toxic herbicide, are stable …
herbicides. Viologen compounds, a type of widely used but highly toxic herbicide, are stable …
Capture of hydroxyl radicals by hydronium cations in water microdroplets
Despite the high stability of bulk water, water microdroplets possess strikingly different
properties, such as the presence of hydroxyl radicals (OH⋅) at the air–water interface …
properties, such as the presence of hydroxyl radicals (OH⋅) at the air–water interface …