3d transition metals for C–H activation
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …
notable applications to material sciences, crop protection, drug discovery, and …
Transition metal-catalyzed C–H amination: scope, mechanism, and applications
Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …
synthetic approach to construct N-functionalized molecules. Over the last few decades …
Aerobic copper-catalyzed organic reactions
SE Allen, RR Walvoord, R Padilla-Salinas… - Chemical …, 2013 - ACS Publications
The chemistry of copper is extremely rich because it can easily access Cu0, CuI, CuII, and
CuIII oxidation states allowing it to act through one-electron or two-electron processes. As a …
CuIII oxidation states allowing it to act through one-electron or two-electron processes. As a …
Bidentate, monoanionic auxiliary-directed functionalization of carbon–hydrogen bonds
O Daugulis, J Roane, LD Tran - Accounts of chemical research, 2015 - ACS Publications
Conspectus In recent years, carbon–hydrogen bond functionalization has evolved from an
organometallic curiosity to a tool used in mainstream applications in the synthesis of …
organometallic curiosity to a tool used in mainstream applications in the synthesis of …
Comproportionation and disproportionation in nickel and copper complexes
CS Day, R Martin - Chemical Society Reviews, 2023 - pubs.rsc.org
Disproportionation and comproportionation reactions have become increasingly important
electron transfer events in organometallic chemistry and catalysis. The renewed interest in …
electron transfer events in organometallic chemistry and catalysis. The renewed interest in …
Copper catalysed Ullmann type chemistry: from mechanistic aspects to modern development
Cu-catalysed arylation reactions devoted to the formation of C–C and C–heteroatom bonds
(Ullmann-type couplings) have acquired great importance in the last decade. This review …
(Ullmann-type couplings) have acquired great importance in the last decade. This review …
Mechanistic development and recent applications of the Chan–Lam amination
Transition metal-mediated formation of C–N bonds is an essential synthetic methodology.
The discovery of the Chan–Lam amination provided a C–N bond forming process that was …
The discovery of the Chan–Lam amination provided a C–N bond forming process that was …
Single atom catalysts for selective methane oxidation to oxygenates
Direct conversion of methane (CH4) to C1–2 liquid oxygenates is a captivating approach to
lock carbons in transportable value-added chemicals, while reducing global warming …
lock carbons in transportable value-added chemicals, while reducing global warming …
High-valent organometallic copper and palladium in catalysis
AJ Hickman, MS Sanford - Nature, 2012 - nature.com
Copper and palladium catalysts are critically important in numerous commercial chemical
processes. Improvements in the activity, selectivity and scope of these catalysts could …
processes. Improvements in the activity, selectivity and scope of these catalysts could …
Overcoming the “Oxidant Problem”: Strategies to Use O2 as the Oxidant in Organometallic C–H Oxidation Reactions Catalyzed by Pd (and Cu)
AN Campbell, SS Stahl - Accounts of Chemical Research, 2012 - ACS Publications
Oxidation reactions are key transformations in organic chemistry because they can increase
chemical complexity and incorporate heteroatom substituents into carbon-based molecules …
chemical complexity and incorporate heteroatom substituents into carbon-based molecules …