3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

Transition metal-catalyzed C–H amination: scope, mechanism, and applications

Y Park, Y Kim, S Chang - Chemical reviews, 2017 - ACS Publications
Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …

Aerobic copper-catalyzed organic reactions

SE Allen, RR Walvoord, R Padilla-Salinas… - Chemical …, 2013 - ACS Publications
The chemistry of copper is extremely rich because it can easily access Cu0, CuI, CuII, and
CuIII oxidation states allowing it to act through one-electron or two-electron processes. As a …

Bidentate, monoanionic auxiliary-directed functionalization of carbon–hydrogen bonds

O Daugulis, J Roane, LD Tran - Accounts of chemical research, 2015 - ACS Publications
Conspectus In recent years, carbon–hydrogen bond functionalization has evolved from an
organometallic curiosity to a tool used in mainstream applications in the synthesis of …

Comproportionation and disproportionation in nickel and copper complexes

CS Day, R Martin - Chemical Society Reviews, 2023 - pubs.rsc.org
Disproportionation and comproportionation reactions have become increasingly important
electron transfer events in organometallic chemistry and catalysis. The renewed interest in …

Copper catalysed Ullmann type chemistry: from mechanistic aspects to modern development

C Sambiagio, SP Marsden, AJ Blacker… - Chemical Society …, 2014 - pubs.rsc.org
Cu-catalysed arylation reactions devoted to the formation of C–C and C–heteroatom bonds
(Ullmann-type couplings) have acquired great importance in the last decade. This review …

Mechanistic development and recent applications of the Chan–Lam amination

MJ West, JWB Fyfe, JC Vantourout… - Chemical …, 2019 - ACS Publications
Transition metal-mediated formation of C–N bonds is an essential synthetic methodology.
The discovery of the Chan–Lam amination provided a C–N bond forming process that was …

Single atom catalysts for selective methane oxidation to oxygenates

P Kumar, TA Al-Attas, J Hu, MG Kibria - ACS nano, 2022 - ACS Publications
Direct conversion of methane (CH4) to C1–2 liquid oxygenates is a captivating approach to
lock carbons in transportable value-added chemicals, while reducing global warming …

High-valent organometallic copper and palladium in catalysis

AJ Hickman, MS Sanford - Nature, 2012 - nature.com
Copper and palladium catalysts are critically important in numerous commercial chemical
processes. Improvements in the activity, selectivity and scope of these catalysts could …

Overcoming the “Oxidant Problem”: Strategies to Use O2 as the Oxidant in Organometallic C–H Oxidation Reactions Catalyzed by Pd (and Cu)

AN Campbell, SS Stahl - Accounts of Chemical Research, 2012 - ACS Publications
Oxidation reactions are key transformations in organic chemistry because they can increase
chemical complexity and incorporate heteroatom substituents into carbon-based molecules …