Molecular architectonic on metal surfaces

JV Barth - Annu. Rev. Phys. Chem., 2007 - annualreviews.org
The engineering of highly organized systems from instructed molecular building blocks
opens up new vistas for the control of matter and the exploration of nanodevice concepts …

Supramolecular assemblies on surfaces: nanopatterning, functionality, and reactivity

DP Goronzy, M Ebrahimi, F Rosei, Arramel, Y Fang… - ACS …, 2018 - ACS Publications
Understanding how molecules interact to form large-scale hierarchical structures on
surfaces holds promise for building designer nanoscale constructs with defined chemical …

Determining structural and chemical heterogeneities of surface species at the single-bond limit

J Xu, X Zhu, S Tan, Y Zhang, B Li, Y Tian, H Shan… - Science, 2021 - science.org
The structure determination of surface species has long been a challenge because of their
rich chemical heterogeneities. Modern tip-based microscopic techniques can resolve …

Single electron transfer in radical ion and radical-mediated organic, materials and polymer synthesis

N Zhang, SR Samanta, BM Rosen, V Percec - Chemical Reviews, 2014 - ACS Publications
The mechanisms of most organic reactions are considered to proceed by two-electron
transfer pathways, even though both biology and radical chemistry rely extensively on one …

Tailoring molecular layers at metal surfaces

L Bartels - Nature chemistry, 2010 - nature.com
The design of networks of organic molecules at metal surfaces, highly attractive for a variety
of applications ranging from molecular electronics to gas sensors to protective coatings, has …

Single-molecule resolution of an organometallic intermediate in a surface-supported Ullmann coupling reaction

W Wang, X Shi, S Wang, MA Van Hove… - Journal of the American …, 2011 - ACS Publications
We have studied the organometallic intermediate of a surface-supported Ullmann coupling
reaction from 4, 4 ″-dibromo-p-terphenyl to poly (para-phenylene) by scanning tunneling …

Synthesis of polyphenylene molecular wires by surface‐confined polymerization

JA Lipton‐Duffin, O Ivasenko, DF Perepichka, F Rosei - small, 2009 - Wiley Online Library
The surface‐mediated synthesis of epitaxially aligned and separated polyphenylene lines
on Cu (110) by exploiting the Ullmann dehalogenation reaction is reported. Scanning …

Bicomponent supramolecular architectures at the vacuum–solid interface

X Bouju, C Mattioli, G Franc, A Pujol… - Chemical …, 2017 - ACS Publications
This review aims at giving the readers the basic concepts needed to understand two-
dimensional bimolecular organizations at the vacuum–solid interface. The first part …

Surface-induced orientation control of CuPc molecules for the epitaxial growth of highly ordered organic crystals on graphene

K **ao, W Deng, JK Keum, M Yoon… - Journal of the …, 2013 - ACS Publications
The epitaxial growth and preferred molecular orientation of copper phthalocyanine (CuPc)
molecules on graphene has been systematically investigated and compared with growth on …

Material-and orientation-dependent reactivity for heterogeneously catalyzed carbon− bromine bond homolysis

H Walch, R Gutzler, T Sirtl, G Eder… - The Journal of Physical …, 2010 - ACS Publications
Adsorption of the brominated aromatic molecule 1, 3, 5-tris (4-bromophenyl) benzene on
different metallic substrates, namely Cu (111), Ag (111), and Ag (110), has been studied by …