Quantum materials with strong spin–orbit coupling: challenges and opportunities for materials chemists
Spin–orbit coupling is a quantum effect that can give rise to exotic electronic and magnetic
states in the compounds of the 4d and 5d transition metals. Exploratory synthesis, chemical …
states in the compounds of the 4d and 5d transition metals. Exploratory synthesis, chemical …
Review of progress in the materials development of Re, Os, and Ir-based double perovskite oxides
In this review, we examine the latest experimental advances in materials science, focusing
primarily on 5d transition metal-based double perovskite oxides, particularly rhenium (Re) …
primarily on 5d transition metal-based double perovskite oxides, particularly rhenium (Re) …
Antiferromagnetic Order Breaks Inversion Symmetry in a Metallic Double Perovskite, Pb2NiOsO6
A polycrystalline sample of Pb2NiOsO6 was synthesized under high-pressure (6 GPa) and
high-temperature (1575 K) conditions. Pb2NiOsO6 crystallizes in a monoclinic double …
high-temperature (1575 K) conditions. Pb2NiOsO6 crystallizes in a monoclinic double …
Spin-density-wave order controlled by uniaxial stress in
The tetragonal heavy-fermion compound CeAuSb 2 (space group P 4/nmm) exhibits
incommensurate spin-density wave (SDW) order below TN≈ 6.5 K with the propagation …
incommensurate spin-density wave (SDW) order below TN≈ 6.5 K with the propagation …
Polar metals in strain-engineered KNbO 3/CaNbO 3 superlattices: a first-principles study
Q Liang, F Zheng, M Li - Physical Chemistry Chemical Physics, 2023 - pubs.rsc.org
Polar metals have generated significant interest since the ferroelectric-like structural
transition in metallic LiOsO3 was discovered. Herein, we report on a strain-modulated polar …
transition in metallic LiOsO3 was discovered. Herein, we report on a strain-modulated polar …
Improper multiferroiclike transition in a metal
Magnetic frustration in insulators often induces cooperative atomic displacements to form a
polar structure with long-range ordered electric dipoles, commonly known as improper …
polar structure with long-range ordered electric dipoles, commonly known as improper …
Magnetically induced metal-insulator transition in
We report on the structural, magnetic, and electronic properties of two new double-
perovskites synthesized under high pressure, Pb 2 CaOsO 6 and Pb 2 ZnOsO 6. Upon …
perovskites synthesized under high pressure, Pb 2 CaOsO 6 and Pb 2 ZnOsO 6. Upon …
Design and Synthesis of a Metallic Polar Aurivillius Oxide Bi2ReO6
Y Li, J Li, S Miao, H Yang, J Li, CJ Kang… - Chemistry of …, 2023 - ACS Publications
The number of reported metallic compounds with polar crystal structures is limited due to the
incompatibility of the acentricity and metallicity. Particularly, metallic oxides with polar crystal …
incompatibility of the acentricity and metallicity. Particularly, metallic oxides with polar crystal …
Coupled magnetic and structural phase transitions in the antiferromagnetic polar metal under pressure
Pb 2 Co Os O 6 is a newly synthesized polar metal in which inversion symmetry is broken by
the magnetic frustration in an antiferromagnetic ordering of Co and Os sublattices. The …
the magnetic frustration in an antiferromagnetic ordering of Co and Os sublattices. The …
Synthesis and Characterization of Noncentrosymmetric Oxides and Intermetallics
C Skaggs - 2024 - search.proquest.com
Inorganic solid-state compounds that lack inversion symmetry in the crystal structures are
defined as non-centrosymmetric (NCS) materials. These compounds have applications in …
defined as non-centrosymmetric (NCS) materials. These compounds have applications in …