Hierarchical porous metal–organic gels and derived materials: from fundamentals to potential applications

JK Wychowaniec, H Saini, B Scheibe… - Chemical Society …, 2022 - pubs.rsc.org
Metal–organic gels (MOGs) emerged as a novel class of functional soft materials in which
the scaffolding framework is fabricated by metal–ligand coordination in combination with …

Chemistry of soft porous crystals: structural dynamics and gas adsorption properties

S Krause, N Hosono, S Kitagawa - … Chemie International Edition, 2020 - Wiley Online Library
In this Minireview, we discuss the fundamental chemistry of soft porous crystals (SPCs) by
characterizing their common structural features and the resulting structural softness and …

[HTML][HTML] Machine learning potentials for metal-organic frameworks using an incremental learning approach

S Vandenhaute, M Cools-Ceuppens… - npj Computational …, 2023 - nature.com
Computational modeling of physical processes in metal-organic frameworks (MOFs) is
highly challenging due to the presence of spatial heterogeneities and complex operating …

The chemistry and applications of flexible porous coordination polymers

N Behera, J Duan, W **, S Kitagawa - EnergyChem, 2021 - Elsevier
Since the late 1990s, much progress has been made in the field of the chemistry of flexible
porous coordination polymers (PCPs). Various PCP architectures have been recognized …

Four-dimensional metal-organic frameworks

JD Evans, V Bon, I Senkovska, HC Lee… - Nature …, 2020 - nature.com
Recognising timescale as an adjustable dimension in porous solids provides a new
perspective to develop novel four-dimensional framework materials. The deliberate design …

Solvent‐induced control over breathing behavior in flexible metal–organic frameworks for natural‐gas delivery

T Kundu, M Wahiduzzaman, BB Shah… - Angewandte …, 2019 - Wiley Online Library
Finding appropriate stimuli for controlling the breathing behavior of flexible metal–organic
frameworks (MOFs) is highly challenging. Herein, we report the solvent‐induced changes in …

Metal-organic frameworks in Russia: From the synthesis and structure to functional properties and materials

MA Agafonov, EV Alexandrov, NA Artyukhova… - Journal of Structural …, 2022 - Springer
Current research fields of metal-organic frameworks (MOFs), which are being developed in
the last 5-10 years by Russian scientific institutions and universities, are generalized. The …

Adaptive Pore Opening to Form Tailored Adsorption Sites in a Cooperatively Flexible Framework Enables Record Inverse Propane/Propylene Separation

RA Klein, LW Bingel, A Halder, M Carter… - Journal of the …, 2023 - ACS Publications
A proposed low-energy alternative to the separation of alkanes from alkenes by energy-
intensive cryogenic distillation is separation by porous adsorbents. Unfortunately, most …

Diverse crystal size effects in covalent organic frameworks

T Ma, L Wei, L Liang, S Yin, L Xu, J Niu, H Xue… - Nature …, 2020 - nature.com
Crystal size effect is of vital importance in materials science by exerting significant influence
on various properties of materials and furthermore their functions. Crystal size effect of …

High-rate nanofluidic energy absorption in porous zeolitic frameworks

Y Sun, SMJ Rogge, A Lamaire, S Vandenbrande… - Nature Materials, 2021 - nature.com
Optimal mechanical impact absorbers are reusable and exhibit high specific energy
absorption. The forced intrusion of liquid water in hydrophobic nanoporous materials, such …