[HTML][HTML] Chemistry of sterically demanding dppf-analogs
Recent advances in the chemistry of bulky bisphosphane ligands related to the dppf motif
are summarized in this review covering the literature from 1981 to 2020 related to over 220 …
are summarized in this review covering the literature from 1981 to 2020 related to over 220 …
Tailoring the Fe→ Pd interaction in cationic Pd (II) complexes via structural variation of the ligand scaffold of sterically demanding dppf-analogs and their P, N …
Two 1, 1′-azaphospha substituted dppf-analogues Fc′(NMe2)(PPh2)(Ph= C6H5, Fc′= 1,
1′-ferrocenediyl, 3a) and Fc′(NMe2)(PMes2)(Mes= 2, 4, 6-Me3C6H2, 3b) have been …
1′-ferrocenediyl, 3a) and Fc′(NMe2)(PMes2)(Mes= 2, 4, 6-Me3C6H2, 3b) have been …
Hybrid materials comprising ferrocene and diaminoborane moieties: linear concatenation versus macrocyclization
JS Schneider, H Helten - Chemical Communications, 2024 - pubs.rsc.org
Combination of borane and diaminoferrocene monomers by Si/B exchange condensation
reactions afforded either diazabora-[3] ferrocenophanes or, via stepwise processes, larger …
reactions afforded either diazabora-[3] ferrocenophanes or, via stepwise processes, larger …
Chalcogen‐Transfer Rearrangement: Exploring Inter‐versus Intramolecular P− P Bond Activation
R Franz, S Nasemann, C Bruhn… - … A European Journal, 2021 - Wiley Online Library
Abstract tert‐Butyl‐substituted diphospha [2] ferrocenophane has been used as a
stereochemically confined diphosphane to explore the addition of O, S, Se and Te. Although …
stereochemically confined diphosphane to explore the addition of O, S, Se and Te. Although …
PBP bridged [3] ferrocenophane: a bisphosphanylborane with a redox trigger
A Lik, D Kargin, S Isenberg, Z Kelemen… - Chemical …, 2018 - pubs.rsc.org
Stereospecific access to the unprecedented P–B–P bridged [3] ferrocenophane Fe
(C5H4PtBu) 2BMes is presented. In contrast to acyclic ferrocenylphosphanes, we find …
(C5H4PtBu) 2BMes is presented. In contrast to acyclic ferrocenylphosphanes, we find …
A Stabilized Bisphosphanylsilylene and Its Heavier Congeners
D Kargin, Z Kelemen, K Krekić… - … A European Journal, 2018 - Wiley Online Library
A bisphosphanylsilylene with [3] ferrocenophane backbone and its heavier analogues are
described in the form of donor adducts. These heterocarbenes can be formed by …
described in the form of donor adducts. These heterocarbenes can be formed by …
Stereochemical alignment in triphospha [3] ferrocenophanes
S Borucki, Z Kelemen, M Maurer… - … A European Journal, 2017 - Wiley Online Library
A series of triphospha [3] ferrocenophanes of the type Fe (C5H4‐PtBu) 2PX with X= H, F, Cl,
Br, I, NEt2, tBu has been prepared and characterized by heteronuclear NMR spectroscopy …
Br, I, NEt2, tBu has been prepared and characterized by heteronuclear NMR spectroscopy …
A new entry towards diastereomeric C 1, C 2, C 3-functionalized [3] ferrocenophanes using a solid state mediated double 1, 4-Michael addition type ring closing …
Unusual diastereomeric C1, C2, C3-functionalized carba [3] ferrocenophanes with two
stereogenic centres have been obtained using a ring closing reaction, based upon …
stereogenic centres have been obtained using a ring closing reaction, based upon …
Bending Ferrocenes with Low Coordinated Bridging Units: The Investigation of Carbenes and Their Analogues with a Ferrocenophane Backbone
[3] ferrocenophanes with X–E–X ansa moieties containing a low coordinated center E
stabilized by adjacent donor units X were studied by density functional theory methods. The …
stabilized by adjacent donor units X were studied by density functional theory methods. The …
Bis‐[3] Ferrocenophanes with Central> E− E'< Bonds (E, E'= P, SiH): Preparation, Properties, and Thermal Activation
S Isenberg, S Weller, D Kargin, S Valić… - …, 2019 - Wiley Online Library
Abstract A series of bis‐[3] ferrocenophanes of the general type Fe (C5H4E') 2E− E
(E'C5H4) 2Fe (E= P, SiH and E'= PtBu, NneoPentyl, NSi (CH3) 3) with an isolobal molecular …
(E'C5H4) 2Fe (E= P, SiH and E'= PtBu, NneoPentyl, NSi (CH3) 3) with an isolobal molecular …