Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects

NF Suremann, BD McCarthy, W Gschwind… - Chemical …, 2023 - ACS Publications
The modularity and synthetic flexibility of metal–organic frameworks (MOFs) have provoked
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …

Implicit solvation methods for catalysis at electrified interfaces

S Ringe, NG Hormann, H Oberhofer… - Chemical Reviews, 2021 - ACS Publications
Implicit solvation is an effective, highly coarse-grained approach in atomic-scale simulations
to account for a surrounding liquid electrolyte on the level of a continuous polarizable …

Bioinspiration in light harvesting and catalysis

AH Proppe, YC Li, A Aspuru-Guzik… - Nature Reviews …, 2020 - nature.com
Capturing and converting solar energy into fuels and feedstocks is a global challenge that
spans numerous disciplines and fields of research. Billions of years of evolution have …

Manganese compounds as water-oxidizing catalysts: from the natural water-oxidizing complex to nanosized manganese oxide structures

MM Najafpour, G Renger, M Hołynska… - Chemical …, 2016 - ACS Publications
All cyanobacteria, algae, and plants use a similar water-oxidizing catalyst for water
oxidation. This catalyst is housed in Photosystem II, a membrane-protein complex that …

Photosynthesis: basics, history and modelling

A Stirbet, D Lazár, Y Guo, G Govindjee - Annals of botany, 2020 - academic.oup.com
Background With limited agricultural land and increasing human population, it is essential to
enhance overall photosynthesis and thus productivity. Oxygenic photosynthesis begins with …

Production of reactive oxygen species by photosystem II as a response to light and temperature stress

P Pospíšil - Frontiers in plant science, 2016 - frontiersin.org
The effect of various abiotic stresses on photosynthetic apparatus is inevitably associated
with formation of harmful reactive oxygen species (ROS). In this review, recent progress on …

Semi-biological approaches to solar-to-chemical conversion

X Fang, S Kalathil, E Reisner - Chemical Society Reviews, 2020 - pubs.rsc.org
This review presents a comprehensive summary of the recent development in semi-artificial
photosynthesis, a biological-material hybrid approach to solar-to-chemical conversion that …

Oxygen and ROS in photosynthesis

S Khorobrykh, V Havurinne, H Mattila, E Tyystjärvi - Plants, 2020 - mdpi.com
Oxygen is a natural acceptor of electrons in the respiratory pathway of aerobic organisms
and in many other biochemical reactions. Aerobic metabolism is always associated with the …

Advancing photosystem II photoelectrochemistry for semi-artificial photosynthesis

JZ Zhang, E Reisner - Nature Reviews Chemistry, 2020 - nature.com
Oxygenic photosynthesis is the primary solar energy-conversion process that supports much
of life on Earth. It is initiated by photosystem II (PSII), an enzyme that extracts electrons from …

The evolution and evolvability of photosystem II

T Oliver, TD Kim, JP Trinugroho… - Annual Review of …, 2023 - annualreviews.org
Photosystem II is the water-oxidizing and O2-evolving enzyme of photosynthesis. How and
when this remarkable enzyme arose are fundamental questions in the history of life that …