Defects in the self-assembly of block copolymers and their relevance for directed self-assembly

W Li, M Müller - Annual review of chemical and biomolecular …, 2015 - annualreviews.org
Block copolymer self-assembly provides a platform for fabricating dense, ordered
nanostructures by encoding information in the chemical architecture of multicomponent …

Orientational order in sphere-forming block copolymer thin films aligned under shear

AP Marencic, MW Wu, RA Register… - Macromolecules, 2007 - ACS Publications
Shear can impart a high degree of orientational order to block copolymer thin films
containing two or more layers of spherical domains, but the orientational order appears to …

Anomalous grain growth in a polycrystalline monolayer of colloidal hard spheres

FA Lavergne, DGAL Aarts, RPA Dullens - Physical Review X, 2017 - APS
Understanding grain growth is key for controlling the microstructure and the mechanical
properties of most polycrystalline materials, including metals, alloys, and ceramics …

Defect formation and coarsening in hexagonal 2D curved crystals

NA Garcia, AD Pezzutti, RA Register, DA Vega… - Soft Matter, 2015 - pubs.rsc.org
In this work we study the processes of defect formation and coarsening of two-dimensional
(2D) curved crystal structures. These processes are found to strongly deviate from their …

Computational characterization of ordered nanostructured surfaces

NM Abukhdeir - Materials Research Express, 2016 - iopscience.iop.org
A vital and challenging task for materials researchers is to determine relationships between
material characteristics and desired properties. While the measurement and assessment of …

Mesostructure of ordered corneal nano-nipple arrays: the role of 5–7 coordination defects

KC Lee, Q Yu, U Erb - Scientific Reports, 2016 - nature.com
Corneal nano-nipple structures consisting of hexagonally arranged protrusions with
diameters around 200 nm have long been known for their antireflection capability and have …

Coupling between mean curvature and textures in block copolymer thin films deposited on curved substrates

DA Vega, LR Gómez, AD Pezzutti, F Pardo, PM Chaikin… - Soft Matter, 2013 - pubs.rsc.org
We study the dynamics of coarsening in a cylinder-forming polystyrene-block-poly (ethylene-
alt-propylene) block copolymer thin film deposited on a topographically patterned substrate …

Crystallization dynamics on curved surfaces

NA García, RA Register, DA Vega, LR Gómez - Physical Review E—Statistical …, 2013 - APS
We study the evolution from a liquid to a crystal phase in two-dimensional curved space. At
early times, while crystal seeds grow preferentially in regions of low curvature, the lattice …

Ordering dynamics of directed self-assembly of block copolymers in periodic two-dimensional fields

W Li, F Qiu, Y Yang, AC Shi - Macromolecules, 2010 - ACS Publications
The ordering dynamics of directed self-assembly of cylinder-forming diblock copolymers is
studied by cell dynamics simulations. The directing field, mimicking chemically or …

Droplet-like Defect Annihilation Mechanisms in Hexagonal Cylinder-Forming Block Copolymers

Y Ren, W Li - ACS Macro Letters, 2022 - ACS Publications
The annihilation of typical individual defects in hexagonal cylinder-forming block copolymers
is investigated using the self-consistent field theory (SCFT) in conjunction with the string …