The influence of iso-butene kinetics on the reactivity of di-isobutylene and iso-octane

N Lokachari, S Panigrahy, G Kukkadapu, G Kim… - Combustion and …, 2020 - Elsevier
The continuous development of a core C 0–C 4 kinetic mechanism generally involves
updating it using reliable kinetics and thermodynamics and may also involve the inclusion of …

Modeling of two-and three-ring aromatics formation in the pyrolysis of toluene

A Matsugi, A Miyoshi - Proceedings of the Combustion Institute, 2013 - Elsevier
A detailed chemical kinetic model for the pyrolysis of toluene and subsequent formation of
polycyclic aromatic hydrocarbons (PAHs) was constructed for the low pressure (∼ 10Torr) …

C7 reaction mechanism and its self-imitation in the kinetic modeling of PAH formation

H **, A Farooq - Combustion and Flame, 2023 - Elsevier
Polycyclic aromatic hydrocarbons (PAHs), serving as critical soot precursors, are formed via
complicated chemical processes, such as the first aromatic ring formation and the aromatic …

[HTML][HTML] Production of aliphatic-linked polycyclic hydrocarbons during radical-driven particle formation from propyne and propene pyrolysis

JA Rundel, KO Johansson, PE Schrader… - Combustion and …, 2023 - Elsevier
We investigated the pyrolysis of propyne and propene using aerosol mass spectrometry
coupled with tunable synchrotron vacuum ultraviolet photoionization. The results show that …

Multiple-well master equation study on the propargyl+ indenyl recombination and subsequent reactions

A Matsugi, S Suzuki - Combustion and Flame, 2024 - Elsevier
The reaction between propargyl and indenyl radicals is investigated focusing primarily on
the reaction pathways leading to the formation of acenaphthylene. The potential energy …

Photochemistry of C3Hp hydrocarbons in Titan's stratosphere revisited

E Hébrard, M Dobrijevic, JC Loison, A Bergeat… - Astronomy & …, 2013 - aanda.org
The description of C 3 hydrocarbon chemistry in current photochemical models of Titan's
atmosphere is found to be far from complete. We have carefully investigated the …

Computational study on the recombination reaction between benzyl and propargyl radicals

A Matsugi, A Miyoshi - International Journal of Chemical …, 2012 - Wiley Online Library
The kinetics and mechanisms of the recombination reaction between benzyl and propargyl
radicals have been computationally investigated by using the B3LYP, CBS‐QB3, and …

Reactions of allylic radicals that impact molecular weight growth kinetics

K Wang, SM Villano, AM Dean - Physical Chemistry Chemical Physics, 2015 - pubs.rsc.org
The reactions of allylic radicals have the potential to play a critical role in molecular weight
growth (MWG) kinetics during hydrocarbon oxidation and/or pyrolysis. Due to their stability …

Measurements of Intermediate Species in Fuel-Rich Oxidation of Ethylene, Toluene, and n-Decane

S Suzuki, A Obuchi, G Kukkadapu, K Kinoshita… - Energy & …, 2021 - ACS Publications
Polycyclic aromatic hydrocarbons (PAHs) are important precursors to the formation of soot
and are also pollutant emissions from combustion devices, including internal combustion …

Thermal decomposition of benzyl radicals: kinetics and spectroscopy in a shock tube

A Matsugi - The Journal of Physical Chemistry A, 2020 - ACS Publications
Understanding the mechanism of high-temperature reactions of aromatic hydrocarbons and
radicals is essential for the modeling of hydrocarbon growth processes in combustion …