Mechanistic studies of transition-metal-catalyzed [2+ 2+ 2] cycloaddition reactions

A Roglans, A Pla-Quintana, M Sola - Chemical Reviews, 2020 - ACS Publications
The development of catalytic methodologies involving the formation of C–C bonds to enable
the generation of cyclic systems constitutes a field of great relevance in synthetic organic …

Indenyl and Allyl Palladate Complexes Bearing N‐Heterocyclic Carbene Ligands: an Easily Accessible Class of New Anticancer Drug Candidates

T Scattolin, I Pessotto, E Cavarzerani… - European Journal of …, 2022 - Wiley Online Library
The mechanochemical syntheses of allyl and indenyl palladate complexes are reported. All
compounds were obtained in quantitative yields and microanalytically pure without the need …

Highly stable silver (i) complexes with cyclen-based ligands bearing sulfide arms: a step toward silver-111 labeled radiopharmaceuticals

M Tosato, M Asti, M Dalla Tiezza, L Orian… - Inorganic …, 2020 - ACS Publications
With a half-life of 7.45 days, silver-111 (βmax 1.04 MeV, E γ 245.4 keV [I γ 1.24%], E γ 342.1
keV [I γ 6.7%]) is a promising candidate for targeted cancer therapy with β–emitters as well …

Unveiling the promising anticancer activity of palladium (ii)–aryl complexes bearing diphosphine ligands: a structure–activity relationship analysis

G Tonon, M Mauceri, E Cavarzerani, R Piccolo… - Dalton …, 2024 - pubs.rsc.org
In continuation of our previous works on the cytotoxic properties of organopalladium
compounds, in this contribution we describe the first systematic study of the anticancer …

Synthesis, Structural Characterization and Antiproliferative Activity of Gold (I) and Gold (III) Complexes Bearing Thioether‐Functionalized N‐Heterocyclic Carbenes

R De Marco, M Dal Grande, M Baron… - European Journal of …, 2021 - Wiley Online Library
A series of gold (I) and gold (III) complexes with N‐heterocyclic carbene ligands
functionalized with a pendant thioether group (NHC‐SR) was synthesized with …

Designing Rh (I)-Half-Sandwich Catalysts for Alkyne [2+ 2+ 2] Cycloadditions

L Orian, FM Bickelhaupt - Synlett, 2021 - thieme-connect.com
Metal-mediated [2+ 2+ 2] cycloadditions of unsaturated molecules to cyclic and polycyclic
organic compounds are a versatile synthetic route affording good yields and selectivity …

[HTML][HTML] In Silico Acetylene [2+ 2+ 2] Cycloadditions Catalyzed by Rh/Cr Indenyl Fragments

S Masood Ahmad, M Dalla Tiezza, L Orian - Catalysts, 2019 - mdpi.com
Metal-catalyzed alkyne [2+ 2+ 2] cycloadditions provide a variety of substantial aromatic
compounds of interest in the chemical and pharmaceutical industries. Herein, the …

Silver (I) and gold (I) complexes with bitriazole‐based N‐heterocyclic carbene ligand: Solid state features and behaviour in solution

A Longhi, M Baron, M Rancan, G Bottaro… - Applied …, 2024 - Wiley Online Library
The coordinating properties of the bis (1, 4‐dimethyl‐1, 2, 4‐triazol‐5‐ylidene) ligand
(abbreviated as bitz) towards silver (I) and gold (I) centres have been explored. The bitz …

Novel catalytic approaches to selective catalytic systhems for the direct synthesis of hydrogen peroxide

F Sandri - 2023 - research.unipd.it
This Thesis is focused on the investigation of supported palladium catalysts for the direct
synthesis of hydrogen peroxide, with particular attention to a novel material supported on a …