Recent Advances in Alkenyl sp2 C–H and C–F Bond Functionalizations: Scope, Mechanism, and Applications
MZ Lu, J Goh, M Maraswami, Z Jia, JS Tian… - Chemical …, 2022 - ACS Publications
Alkenes and their derivatives are featured widely in a variety of natural products,
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …
Bidentate directing groups: an efficient tool in C–H bond functionalization chemistry for the expedient construction of C–C bonds
S Rej, Y Ano, N Chatani - Chemical reviews, 2020 - ACS Publications
During the past decades, synthetic organic chemistry discovered that directing group
assisted C–H activation is a key tool for the expedient and siteselective construction of C–C …
assisted C–H activation is a key tool for the expedient and siteselective construction of C–C …
3d transition metals for C–H activation
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …
notable applications to material sciences, crop protection, drug discovery, and …
3d metallaelectrocatalysis for resource economical syntheses
Resource economy constitutes one of the key challenges for researchers and practitioners
in academia and industries, in terms of rising demand for sustainable and green synthetic …
in academia and industries, in terms of rising demand for sustainable and green synthetic …
Cp* M-catalyzed direct annulation with terminal alkynes and their surrogates for the construction of multi-ring systems
Y Nishii, M Miura - ACS Catalysis, 2020 - ACS Publications
Transition-metal-catalyzed C–H activation followed by oxidative cyclization with unsaturated
coupling partners has been a valuable synthetic tool for the multiring molecular scaffolds …
coupling partners has been a valuable synthetic tool for the multiring molecular scaffolds …
Cobalt (II)-catalyzed CH functionalization using an N, N′-bidentate directing group
Y Kommagalla, N Chatani - Coordination Chemistry Reviews, 2017 - Elsevier
This review focuses on cobalt-catalyzed, chelation-assisted Csingle bondH functionalization
reactions in which an N, N′-bidentate directing group is used. Cobalt complexes are now …
reactions in which an N, N′-bidentate directing group is used. Cobalt complexes are now …
Recent advances in transition metal-catalyzed heteroannulative difunctionalization of alkenes via C–H activation for the synthesis of heterocycles
J Liu, X **ao, Y Lai, Z Zhang - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
Heterocyclic compounds are the fundamental structural motifs distributed in natural
products, pharmaceuticals and biologically active compounds. Thus, there is increasing …
products, pharmaceuticals and biologically active compounds. Thus, there is increasing …
C–H bond functionalization by high-valent cobalt catalysis: current progress, challenges and future perspectives
L Lukasevics, A Cizikovs, L Grigorjeva - Chemical Communications, 2021 - pubs.rsc.org
Over the last decade, high-valent cobalt catalysis has earned a place in the spotlight as a
valuable tool for C–H activation and functionalization. Since the discovery of its unique …
valuable tool for C–H activation and functionalization. Since the discovery of its unique …
Cobalt-catalyzed enantioselective C–H/N–H annulation of aryl sulfonamides with allenes or alkynes: facile access to C–N axially chiral sultams
XJ Si, X Zhao, J Wang, X Wang, Y Zhang, D Yang… - Chemical …, 2023 - pubs.rsc.org
Herein we report a cobalt-catalyzed enantioselective C–H/N–H annulation of aryl
sulfonamides with allenes and alkynes, using either chemical or electrochemical oxidation …
sulfonamides with allenes and alkynes, using either chemical or electrochemical oxidation …
Electrooxidative allene annulations by mild cobalt-catalyzed C–H activation
Versatile cobalt catalysis enabled electrochemical C–H activation with allenes. Thus, allene
annulations were accomplished in terms of C–H/N–H functionalizations with excellent levels …
annulations were accomplished in terms of C–H/N–H functionalizations with excellent levels …