Recent Advances in Alkenyl sp2 C–H and C–F Bond Functionalizations: Scope, Mechanism, and Applications

MZ Lu, J Goh, M Maraswami, Z Jia, JS Tian… - Chemical …, 2022 - ACS Publications
Alkenes and their derivatives are featured widely in a variety of natural products,
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …

Bidentate directing groups: an efficient tool in C–H bond functionalization chemistry for the expedient construction of C–C bonds

S Rej, Y Ano, N Chatani - Chemical reviews, 2020 - ACS Publications
During the past decades, synthetic organic chemistry discovered that directing group
assisted C–H activation is a key tool for the expedient and siteselective construction of C–C …

3d transition metals for C–H activation

P Gandeepan, T Müller, D Zell, G Cera… - Chemical …, 2018 - ACS Publications
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

3d metallaelectrocatalysis for resource economical syntheses

P Gandeepan, LH Finger, TH Meyer… - Chemical Society …, 2020 - pubs.rsc.org
Resource economy constitutes one of the key challenges for researchers and practitioners
in academia and industries, in terms of rising demand for sustainable and green synthetic …

Cp* M-catalyzed direct annulation with terminal alkynes and their surrogates for the construction of multi-ring systems

Y Nishii, M Miura - ACS Catalysis, 2020 - ACS Publications
Transition-metal-catalyzed C–H activation followed by oxidative cyclization with unsaturated
coupling partners has been a valuable synthetic tool for the multiring molecular scaffolds …

Cobalt (II)-catalyzed CH functionalization using an N, N′-bidentate directing group

Y Kommagalla, N Chatani - Coordination Chemistry Reviews, 2017 - Elsevier
This review focuses on cobalt-catalyzed, chelation-assisted Csingle bondH functionalization
reactions in which an N, N′-bidentate directing group is used. Cobalt complexes are now …

Recent advances in transition metal-catalyzed heteroannulative difunctionalization of alkenes via C–H activation for the synthesis of heterocycles

J Liu, X **ao, Y Lai, Z Zhang - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
Heterocyclic compounds are the fundamental structural motifs distributed in natural
products, pharmaceuticals and biologically active compounds. Thus, there is increasing …

C–H bond functionalization by high-valent cobalt catalysis: current progress, challenges and future perspectives

L Lukasevics, A Cizikovs, L Grigorjeva - Chemical Communications, 2021 - pubs.rsc.org
Over the last decade, high-valent cobalt catalysis has earned a place in the spotlight as a
valuable tool for C–H activation and functionalization. Since the discovery of its unique …

Cobalt-catalyzed enantioselective C–H/N–H annulation of aryl sulfonamides with allenes or alkynes: facile access to C–N axially chiral sultams

XJ Si, X Zhao, J Wang, X Wang, Y Zhang, D Yang… - Chemical …, 2023 - pubs.rsc.org
Herein we report a cobalt-catalyzed enantioselective C–H/N–H annulation of aryl
sulfonamides with allenes and alkynes, using either chemical or electrochemical oxidation …

Electrooxidative allene annulations by mild cobalt-catalyzed C–H activation

TH Meyer, JCA Oliveira, SC Sau, NWJ Ang… - ACS …, 2018 - ACS Publications
Versatile cobalt catalysis enabled electrochemical C–H activation with allenes. Thus, allene
annulations were accomplished in terms of C–H/N–H functionalizations with excellent levels …