Confusion is a novel concept of isomerism in porphyrin chemistry, delivering a steady
stream of new chemistry since the discovery of N-confused porphyrin, a porphyrin mutant, in …

Due to enthralling applications in various fields and augmenting fundamental wisdom, π-
conjugated macrocycles in general and porphyrin systems in particular are constantly …

Enhanced thermodynamic stability is a fundamental characteristic of aromatic molecules, yet
most previous studies of aromatic stabilization energy (ASE) have been limited to small rings …

Large π‐conjugated systems are key in the area of molecular materials. Herein, we prepare
via AuI‐catalyzed cyclization a series of fully π‐conjugated anthracene‐fused oligo …

3, 6-Carbazole precursors were used to prepare an octaphyrin. The conformation and
electronic structure of the system could be modulated through trifluoroacetate (TFA) …

Crownphyrins are hybrid macrocycles combining structural features of porphyrin and crown
ethers. The molecular architecture renders them an intriguing class of hosts capable of …

Herein, we report the synthesis of a novel carbaporphyrin incorporating perylene diimide
(PDI) and dipyrromethane units. The twisted plane of the PDI subunits imbues …

A non‐aromatic expanded carbaporphyrinoid, incorporating two built‐in 2, 7‐pyrenylene
moieties was synthesized. The intrinsically labile structure was demonstrated by proton …

The unique environment within the core of carbaporphyrinoid systems provides a platform to
explore unusual organometallic chemistry. The ability of these structures to form stable …

Abstract The oxidation of 10, 15‐diaryl‐21‐carba‐23‐selenaporphyrinoids resulted in the
creation of dyads. The dimerization process follows a [5+ 2] cycloaddition path with the …