Mechanochemistry: new tools to navigate the uncharted territory of “impossible” reactions
F Cuccu, L De Luca, F Delogu, E Colacino… - …, 2022 - Wiley Online Library
Mechanochemical transformations have made chemists enter unknown territories, forcing a
different chemistry perspective. While questioning or revisiting familiar concepts belonging …
different chemistry perspective. While questioning or revisiting familiar concepts belonging …
Continuous‐flow technology—a tool for the safe manufacturing of active pharmaceutical ingredients
In the past few years, continuous‐flow reactors with channel dimensions in the micro‐or
millimeter region have found widespread application in organic synthesis. The characteristic …
millimeter region have found widespread application in organic synthesis. The characteristic …
Recent advances in the transition metal catalyzed carbonylation of alkynes, arenes and aryl halides using CO surrogates
Transition metal catalyzed carbonylation reactions using carbon monoxide as the C-1
source have occupied an all important position in catalysis which is subsequently related to …
source have occupied an all important position in catalysis which is subsequently related to …
Photoinduced copper-catalyzed radical aminocarbonylation of cycloketone oxime esters
B Lu, Y Cheng, LY Chen, JR Chen, WJ ** CO gas-free
carbonylation reactions and the application of carbonylation reactions in the synthesis of …
carbonylation reactions and the application of carbonylation reactions in the synthesis of …
Chloroform as a Carbon Monoxide Precursor: In or Ex Situ Generation of CO for Pd-Catalyzed Aminocarbonylations
SN Gockel, KL Hull - Organic letters, 2015 - ACS Publications
Conditions for the rapid hydrolysis of chloroform to carbon monoxide (CO) using
heterogeneous CsOH· H2O are described. CO and 13CO can be generated cleanly and …
heterogeneous CsOH· H2O are described. CO and 13CO can be generated cleanly and …
State-of-the-art palladium-catalyzed alkoxycarbonylations
R Sang, Y Hu, R Razzaq, R Jackstell… - Organic Chemistry …, 2021 - pubs.rsc.org
Palladium-catalyzed alkoxycarbonylation reactions allow for the efficient conversion of
widely available unsaturated compounds, CO and alcohols into the corresponding …
widely available unsaturated compounds, CO and alcohols into the corresponding …
Transition-metal-catalyzed transfer carbonylation with HCOOH or HCHO as non-gaseous C1 source
J Cao, ZJ Zheng, Z Xu, LW Xu - Coordination Chemistry Reviews, 2017 - Elsevier
While carbon monoxide (CO) gas has been extensively applied in the bulk chemical
industry, its intrinsic properties such as high toxicity, flammability, and special equipment …
industry, its intrinsic properties such as high toxicity, flammability, and special equipment …
Palladium-catalyzed selective generation of CO from formic acid for carbonylation of alkenes
R Sang, P Kucmierczyk, K Dong, R Franke… - Journal of the …, 2018 - ACS Publications
A general and selective palladium-catalyzed alkoxycarbonylation of all kinds of alkenes with
formic acid (HCOOH, FA) is described. Terminal, di-, tri-, and tetra-substituted including …
formic acid (HCOOH, FA) is described. Terminal, di-, tri-, and tetra-substituted including …