Combined hydrogen and alkane production by photocatalytic decarboxylative C–C homocoupling of fatty acid by constructing a hydrogen-deficient catalytic interface

X Li, Y Peng, Z Huang, G Feng, L Kong, H Jiang… - ACS …, 2024 - ACS Publications
Decarboxylation of biomass-derived fatty acids provides an important method for the
production of value-added alkane fuels and chemicals. Here, selective decarboxylative C–C …

Elucidation of the Roles of Water on the Reactivity of Surface Intermediates in Carboxylic Acid Ketonization on TiO2

F Lin, W Hu, NR Jaegers, F Gao, JZ Hu… - Journal of the …, 2022 - ACS Publications
The effects of water on the carboxylic acid ketonization reaction over solid Lewis-acid
catalysts were examined by nuclear magnetic resonance (NMR) spectroscopy, diffuse …

Anatase TiO 2 nanomaterials are much more effective in enhancing hydrolysis of organophosphorus compounds than their rutile counterparts

T Li, Y Ju, T Du, C Jiang, T Zhang… - Environmental Science …, 2024 - pubs.rsc.org
Titanium dioxide (TiO2) nanoparticles, originating from both natural and anthropogenic
sources, are ubiquitous in the environment. Growing evidence shows that TiO2 can …

Ketonization of propionic acid over TS-1 and Ti-Beta zeolites: Mechanism and effects of topology and hydrophobicity

Z Yang, Q Yu, H Wang, Q Ge, X Zhu - Journal of Catalysis, 2024 - Elsevier
Ketonization of propionic acid has been investigated on Lewis acidic TS-1 and Ti-Beta
zeolites to understand the reaction mechanism and effects of pore topology and …

[PDF][PDF] Approaches for the synthesis of high-melting waxes: a review

XL Lang, ST Lei, BL Li, XH Li, B Ma… - Acta Phys. Chim. Sin, 2022 - whxb.pku.edu.cn
High-melting hydrocarbon waxes (melting point:> 80 C), consisting of saturated alkanes with
carbon numbers greater than 40, exhibit unique features including high melting points, high …

The Underlying Catalytic Role of Oxygen Vacancies in Fatty Acid Methyl Esters Ketonization over TiOx Catalysts

M Yazdanpanah, M Fereidooni, V Márquez… - …, 2024 - Wiley Online Library
Recently, interest in converting bio‐derived fatty acid methyl esters (FAMEs) into added‐
value products has significantly increased. The selectivity of ketonization reaction in the …

Crystal facet dependence of the ketonization of propionic acid on anatase TiO 2

J Huang, L Li, X Wu, Y Guo, Z Yang, H Wang… - Catalysis Science & …, 2023 - pubs.rsc.org
Exploring reactions on well-defined surfaces may contribute to a better understanding of
structure–activity relationships for metal oxide-mediated reactions. Herein, anatase TiO2 …

The Role of Surface Complexes in Ketene Formation from Fatty Acids via Pyrolysis over Silica: from Platform Molecules to Waste Biomass

LR Azizova, TV Kulik, BB Palianytsia… - Journal of the …, 2023 - ACS Publications
Fatty acids (FA) are the main constituents of lipids and oil crop waste, considered to be a
promising 2G biomass that can be converted into ketenes via catalytic pyrolysis. Ketenes are …

Conversion of Acetic Acid Over Metal Oxide. Catalysts: An In-situ DRIFTS and Reaction. Pathways Study

P Tingelstad, RL Peters, SK Regli, D Chen - Catalysis Today, 2024 - Elsevier
This study explores the selective ketonization of acetic acid on TiO 2, ZrO 2, and HfO 2
catalysts, focusing on the vapour phase conversion of acetic acid and its subsequent …

Role of Na in the stability enhancement of CeO2 catalysts for ketonization of propionic acid

Z Liu, Y Guo, H Wang, X Zhu - Applied Catalysis A: General, 2024 - Elsevier
A series of CeO 2 catalysts with varying Na content were tested for vapor-phase ketonization
of propionic acid at 350° C. Na+ diffuses into the CeO 2 lattice and excess NaO x …