The amide functionality is an important and pervasive structural motif in pharmacologically
active molecules, agrochemicals, peptides, and polymers. 1 Representative …

Multisubstituted guanidines have received much attention because of important applications
in many fields, such as pharmaceutics, organometallic and coordination chemistry, and …

Recent advances in the carbonylative synthesis of heterocycles by using diverse CO
surrogates as sources of CO are summarized and discussed. The merger of carbonylative …

A palladium-catalyzed CO gas-free carbonylative Sonogashira/cyclization sequence for the
preparation of functionalized 4-quinolones from 2-iodoanilines and alkynes via two different …

The development of catalytic carbonylation reactions has increased considerably. Although
many reviews/chapters/books on carbonylation reactions have been published, summaries …

This account summarizes Pd (0)-catalyzed Mo (CO) 6-mediated gas-free carbonylative
reactions published in the period October 2011 to May 2018. Presented reactions include …

Benzodiazines (diazonaphthalenes with both nitrogens in the same ring)–cinnolines (1, 2-
benzodiazine), quinazolines (1, 3-benzodiazine), phthalazines (2, 3-benzodiazine) and …

A palladium-catalyzed three-component reaction of bis-(2-iodoaryl) carbodiimide,
isocyanide, and amine gives rise to quinazolino [3, 2-a] quinazolines and related …

A novel and efficient route for the preparation of quinazolin-4 (3H)-imines via a palladium-
catalyzed three-component reaction of carbodiimide, isocyanide, and nucleophile is …

We report a Pd-catalyzed three-component reaction of 2-bromoanilines, carbon dioxide, and
isocyanides. The combination of these two readily available C1-reactants, featuring a huge …