This review summarizes the current state-of-the-art procedures in terms of the preparation of
N-arylindoles. After a short introduction, the transition-metal-free procedures available for …

The Ni-catalyzed Csp2–N cross-coupling of NH substrates and (hetero) aryl (pseudo)
halides for the synthesis of (hetero) anilines is in the midst of a resurgence. Reactivity …

Carbazole is a heterocyclic aromatic organic compound that has vast applications in
pharmaceuticals, and in biological and material sciences. Carbazole derivatives show …

The use of (L) Ni (o-tolyl) Cl precatalysts (L= PAd-DalPhos or CyPAd-DalPhos) enables the
C (sp 2)–O cross-coupling of primary, secondary, or tertiary aliphatic alcohols with (hetero) …

The development of Ni‐catalyzed C− N cross‐couplings of sulfonamides with (hetero) aryl
chlorides is reported. These transformations, which were previously achievable only with Pd …

Interest in replacing palladium catalysts with base metals resulted in the development of a
24-reaction screening platform for identifying nickel-catalyzed Suzuki–Miyaura reaction …

Herein we report a cost‐effective synthetic approach for C− N cross‐coupling reactions of a
broad array of nitrogen nucleophiles and aryl halides under mild conditions. These reactions …

We report a versatile method for cross-coupling of NH-sulfoximines with (hetero) aryl
chlorides, as well as bromide and sulfonate electrophiles, that makes use of the air-stable …

A general and efficient Ni-catalyzed coupling of challenging aryl chlorides and in situ
generated aliphatic and aromatic thiolates is described. The employed on-cycle, air-stable …

Despite recent progress regarding the metal-catalyzed C–N cross-coupling of (hetero) aryl
(pseudo) halides with NH substrates, such transformations involving sulfinamide …