Stoichiometric and catalytic transition-metal reactions have attracted great interest for their
many applications in industrial and synthetic processes. Transition-metal reactions are …

The synthetic potential and the mechanistic aspects of inorganic insertion reactions of
carbon monoxide, especially into metal‐carbon σ‐bonds, are considered. Reactions of this …

The iridium/iodide-catalyzed carbonylation of methanol to acetic acid is promoted by
carbonyl complexes of W, Re, Ru, and Os and simple iodides of Zn, Cd, Hg, Ga, and In …

Conclusion This Account describes how antibodies specific for nicotine and its metabolites
and for various prosta-glandins and their metabolites have been used to de-velop sensitive …

Publisher Summary This chapter discusses metal–isocyanide chemistry. In the interim,
reviews have appeared on specific aspects of isocyanide chemistry. The generally accepted …

The great expansion of synthetic organometallic chemistry has been accompanied to a
lesser extent by an interest in the kinetics and mechanism of organo-metallic reactions …

Publisher Summary This chapter focuses on the insertion of carbon monoxide (CO) into
transition metal–carbon σ bonds. An attempt is made at a complete literature coverage of the …

Prebiotic organic synthesis catalyzed by Earth-abundant metal sulfides is a key process for
understanding the evolution of biochemistry from inorganic molecules, yet the catalytic …

Ion pairs [Cp* 2Sc]+[HB (p-C6F4R) 3]−(R= F, 1-F; R= H, 1-H) were prepared and shown to
be unreactive toward D2 and α-olefins, leading to the conclusion that no back-transfer of …

This article is not a comprehensive review of CO substitution of metal carbonyls, it is instead
a report of research carried out in our laboratory on this topic during the past 34 years …