Activation and conversion of alkanes in the confined space of zeolite-type materials

P Del Campo, C Martínez, A Corma - Chemical Society Reviews, 2021 - pubs.rsc.org
Microporous zeolite-type materials, with crystalline porous structures formed by well-defined
channels and cages of molecular dimensions, have been widely employed as …

Automatic mechanism and kinetic model generation for gas‐and solution‐phase processes: a perspective on best practices, recent advances, and future challenges

R Van de Vijver, NM Vandewiele… - … Journal of Chemical …, 2015 - Wiley Online Library
Completely automated mechanism generation of detailed kinetic models is within reach in
the coming decade. The recent developments in this field of chemical reaction engineering …

Impact of the spatial organization of bifunctional metal–zeolite catalysts on the hydroisomerization of light alkanes

K Cheng, LI van der Wal, H Yoshida… - Angewandte …, 2020 - Wiley Online Library
Improving product selectivity by controlling the spatial organization of functional sites at the
nanoscale is a critical challenge in bifunctional catalysis. We present a series of composite …

Influence of Nanoscale Intimacy and Zeolite Micropore Size on the Performance of Bifunctional Catalysts for n-Heptane Hydroisomerization

J Oenema, J Harmel, RP Vélez, MJ Meijerink… - ACS …, 2020 - ACS Publications
In this study, Pt nanoparticles on zeolite/γ-Al2O3 composites (50/50 wt) were located either
in the zeolite or on the γ-Al2O3 binder, hereby varying the average distance (intimacy) …

[HTML][HTML] Shape selectivity in linear paraffins hydroconversion in 10-membered-ring pore zeolites

D Romero, R Rohling, L Meng, M Rigutto… - Journal of …, 2021 - Elsevier
Pd/zeolite-catalyzed hydroconversion of n-hexadecane (nC 16) and n-heptane (nC 7) was
studied for 10MR (ZSM-5, ZSM-22), 12MR (ZSM-12), and EMM-23 (21MR× 10MR) zeolites …

Nature‐Inspired, Computer‐Assisted Optimization of Hierarchically Structured Zeolites

MO Coppens, T Weissenberger… - Advanced Materials …, 2021 - Wiley Online Library
Zeolite catalysis is often affected by transport limitations, which significantly influence overall
performance. Introducing wide pores as molecular transport highways can reduce transport …

[HTML][HTML] Kinetic modeling of catalytic olefin cracking and methanol-to-olefins (MTO) over zeolites: a review

S Standl, O Hinrichsen - Catalysts, 2018 - mdpi.com
The increasing demand for lower olefins requires new production routes besides steam
cracking and fluid catalytic cracking (FCC). Furthermore, less energy consumption, more …

Information-driven catalyst design based on high-throughput intrinsic kinetics

K Van der Borght, K Toch, VV Galvita, JW Thybaut… - Catalysts, 2015 - mdpi.com
A novel methodology is presented for more comprehensive catalyst development by
maximizing the acquired information rather than relying on statistical methods or tedious …

Influence of distributed pore size and porosity on MTO catalyst particle performance: Modeling and simulation

LT Zhu, WY Ma, ZH Luo - Chemical Engineering Research and Design, 2018 - Elsevier
This modeling study investigates the influence of spatially distributed pore size and porosity
on diffusional and reactive features inside the methanol-to-olefin (MTO) porous catalyst …

Optimal design of hierarchically structured ZSM‐5 zeolites for n‐hexane isomerization

Q Zhang, X Liu, S Hu, G Ye, X Zhou, W Yuan - AIChE Journal, 2021 - Wiley Online Library
Although great progress has been made in the synthesis of hierarchically structured zeolites
(HSZs), the optimal design of HSZs is still very challenging due to the lack of mathematical …