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Identification of opportunities for integrating chemical processes for carbon (dioxide) utilization to nuclear power plants
The energy and industrial sectors are responsible for more than 75% of global carbon
dioxide emissions, which are primary contributors to climate change. Decarbonization …
dioxide emissions, which are primary contributors to climate change. Decarbonization …
[HTML][HTML] Astrochemically relevant radicals and radical–molecule complexes: A new insight from matrix isolation
VI Feldman - International Journal of Molecular Sciences, 2023 - mdpi.com
The reactive open-shell species play a very important role in the radiation-induced
molecular evolution occurring in the cold areas of space and presumably leading to the …
molecular evolution occurring in the cold areas of space and presumably leading to the …
Photoelectron photoion coincidence spectroscopy provides mechanistic insights in fuel synthesis and conversion
Clean combustion, ie, the reduction of NOx and soot emissions, and carbon neutrality,
achieved in part by biofuel synthesis, are major milestones in the transition to a sustainable …
achieved in part by biofuel synthesis, are major milestones in the transition to a sustainable …
Formation and Evolution of H2C3O+• Radical Cations: A Computational and Matrix Isolation Study
The family of isomeric H2C3O+• radical cations is of great interest for physical organic
chemistry and chemistry occurring in extraterrestrial media. In this work, we have …
chemistry and chemistry occurring in extraterrestrial media. In this work, we have …
Infrared spectroscopy of the α-hydroxyethyl radical isolated in cryogenic solid media
The α-hydroxyethyl radical (CH 3· CHOH, 2 A) is a key intermediate in ethanol biochemistry,
combustion, atmospheric chemistry, radiation chemistry, and astrochemistry. Experimental …
combustion, atmospheric chemistry, radiation chemistry, and astrochemistry. Experimental …
Matrix isolation model studies on the radiation-induced transformations of small molecules of astrochemical and atmospheric interest
VI Feldman, SV Ryazantsev, EV Saenko… - Radiation Physics and …, 2016 - Elsevier
The radiation-induced transformations of small molecules at low temperatures play an
important role in the interstellar, planetary and atmospheric chemistry. This work presents a …
important role in the interstellar, planetary and atmospheric chemistry. This work presents a …
Conformational switching of HOCO radical: Selective vibrational excitation and hydrogen-atom tunneling
SV Ryazantsev, VI Feldman… - Journal of the American …, 2017 - ACS Publications
Conformers of carboxyl radical (HOCO) have been studied by IR spectroscopy in argon and
nitrogen matrices. In an argon matrix, only the lower-energy conformer trans-HOCO is …
nitrogen matrices. In an argon matrix, only the lower-energy conformer trans-HOCO is …
The Radiation Chemistry of NH3···CO Complex in Cryogenic Media as Studied by Matrix Isolation
AD Volosatova, DA Tyurin… - The Journal of Physical …, 2022 - ACS Publications
The NH3··· CO complex can be considered an important building block for cold synthetic
astrochemistry leading to the formation of complex organic molecules, including key …
astrochemistry leading to the formation of complex organic molecules, including key …
Radiation-induced transformations of matrix-isolated ethanol molecules at cryogenic temperatures: an FTIR study
Ethanol (C2H5OH) is one of the most common alcohol molecules observed in various space
media (molecular clouds, star formation regions, and, highly likely, interstellar ices), where it …
media (molecular clouds, star formation regions, and, highly likely, interstellar ices), where it …
Direct evidence for a radiation-induced synthesis of acetonitrile and isoacetonitrile from a 1: 1 CH 4⋯ HCN complex at cryogenic temperatures: is it a missing link …
AD Volosatova, MA Lukianova, PV Zasimov… - Physical Chemistry …, 2021 - pubs.rsc.org
Nitriles are important constituents of extraterrestrial media. Nitriles are supposed to play a
crucial role in prebiotic chemistry occurring in the interstellar medium. In this work, we have …
crucial role in prebiotic chemistry occurring in the interstellar medium. In this work, we have …