Identification of opportunities for integrating chemical processes for carbon (dioxide) utilization to nuclear power plants

MM Ramirez-Corredores, LA Diaz, AM Gaffney… - … and Sustainable Energy …, 2021 - Elsevier
The energy and industrial sectors are responsible for more than 75% of global carbon
dioxide emissions, which are primary contributors to climate change. Decarbonization …

[HTML][HTML] Astrochemically relevant radicals and radical–molecule complexes: A new insight from matrix isolation

VI Feldman - International Journal of Molecular Sciences, 2023 - mdpi.com
The reactive open-shell species play a very important role in the radiation-induced
molecular evolution occurring in the cold areas of space and presumably leading to the …

Photoelectron photoion coincidence spectroscopy provides mechanistic insights in fuel synthesis and conversion

P Hemberger, A Bodi, T Bierkandt, M Köhler… - Energy & …, 2021 - ACS Publications
Clean combustion, ie, the reduction of NOx and soot emissions, and carbon neutrality,
achieved in part by biofuel synthesis, are major milestones in the transition to a sustainable …

Formation and Evolution of H2C3O+• Radical Cations: A Computational and Matrix Isolation Study

PV Zasimov, DA Tyurin, SV Ryazantsev… - Journal of the …, 2022 - ACS Publications
The family of isomeric H2C3O+• radical cations is of great interest for physical organic
chemistry and chemistry occurring in extraterrestrial media. In this work, we have …

Infrared spectroscopy of the α-hydroxyethyl radical isolated in cryogenic solid media

PV Zasimov, AD Volosatova, S Góbi… - The Journal of …, 2024 - pubs.aip.org
The α-hydroxyethyl radical (CH 3· CHOH, 2 A) is a key intermediate in ethanol biochemistry,
combustion, atmospheric chemistry, radiation chemistry, and astrochemistry. Experimental …

Matrix isolation model studies on the radiation-induced transformations of small molecules of astrochemical and atmospheric interest

VI Feldman, SV Ryazantsev, EV Saenko… - Radiation Physics and …, 2016 - Elsevier
The radiation-induced transformations of small molecules at low temperatures play an
important role in the interstellar, planetary and atmospheric chemistry. This work presents a …

Conformational switching of HOCO radical: Selective vibrational excitation and hydrogen-atom tunneling

SV Ryazantsev, VI Feldman… - Journal of the American …, 2017 - ACS Publications
Conformers of carboxyl radical (HOCO) have been studied by IR spectroscopy in argon and
nitrogen matrices. In an argon matrix, only the lower-energy conformer trans-HOCO is …

The Radiation Chemistry of NH3···CO Complex in Cryogenic Media as Studied by Matrix Isolation

AD Volosatova, DA Tyurin… - The Journal of Physical …, 2022 - ACS Publications
The NH3··· CO complex can be considered an important building block for cold synthetic
astrochemistry leading to the formation of complex organic molecules, including key …

Radiation-induced transformations of matrix-isolated ethanol molecules at cryogenic temperatures: an FTIR study

PV Zasimov, EV Sanochkina, DA Tyurin… - Physical Chemistry …, 2023 - pubs.rsc.org
Ethanol (C2H5OH) is one of the most common alcohol molecules observed in various space
media (molecular clouds, star formation regions, and, highly likely, interstellar ices), where it …

Direct evidence for a radiation-induced synthesis of acetonitrile and isoacetonitrile from a 1: 1 CH 4⋯ HCN complex at cryogenic temperatures: is it a missing link …

AD Volosatova, MA Lukianova, PV Zasimov… - Physical Chemistry …, 2021 - pubs.rsc.org
Nitriles are important constituents of extraterrestrial media. Nitriles are supposed to play a
crucial role in prebiotic chemistry occurring in the interstellar medium. In this work, we have …