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The chalcogen bond in crystalline solids: A world parallel to halogen bond
Conspectus The distribution of the electron density around covalently bonded atoms is
anisotropic, and this determines the presence, on atoms surface, of areas of higher and …
anisotropic, and this determines the presence, on atoms surface, of areas of higher and …
Organic cocrystals: beyond electrical conductivities and field‐effect transistors (FETs)
Organic cocrystals based on noncovalent intermolecular interactions (weak interactions)
have aroused interest owing to their unpredicted and versatile chemicophysical properties …
have aroused interest owing to their unpredicted and versatile chemicophysical properties …
Hypervalent Iodine (III) compounds as biaxial halogen bond donors
F Heinen, E Engelage, CJ Cramer… - Journal of the American …, 2020 - ACS Publications
“Hypervalent” iodine (III) derivatives have been established as powerful reagents in organic
transformations, but so far only a handful of studies have addressed their potential use as …
transformations, but so far only a handful of studies have addressed their potential use as …
Iodine (III)‐Based Halogen Bond Donors: Properties and Applications
Halogen bonding, the non‐covalent interaction of Lewis bases with an electron‐deficient
region of halogen substituents, received increased attention recently. Consequently, the …
region of halogen substituents, received increased attention recently. Consequently, the …
Zwitterionic iodonium species afford halogen bond-based porous organic frameworks
Porous architectures characterized by parallel channels arranged in honeycomb or
rectangular patterns are identified in two polymorphic crystals of a zwitterionic 4 …
rectangular patterns are identified in two polymorphic crystals of a zwitterionic 4 …
Noncovalent Chelation by Halogen Bonding in the Design of Metal-Containing Arrays: Assembly of Double σ-Hole Donating Halolium with CuI-Containing O,O …
Five new copper (I) complexes─ composed of the paired dibenzohalolium and [CuL2]−(L=
1, 2, 4-oxadiazolate) counterions in which O, O-atoms of the anion are simultaneously linked …
1, 2, 4-oxadiazolate) counterions in which O, O-atoms of the anion are simultaneously linked …
A Halogen‐Bond‐Driven Artificial Chloride‐Selective Channel Constructed from 5‐Iodoisophthalamide‐based Molecules
Despite considerable emphasis on advancing artificial ion channels, progress is constrained
by the limited availability of small molecules with the necessary attributes of self‐assembly …
by the limited availability of small molecules with the necessary attributes of self‐assembly …
C (sp3) atoms as tetrel bond donors: A crystallographic survey
The σ-hole and π-hole interactions allow for a systematic understanding of some features of
the attractive interactions involving elements of groups 13–18 of the periodic table and of …
the attractive interactions involving elements of groups 13–18 of the periodic table and of …
Diaryliodonium as a double σ-hole donor: The dichotomy of thiocyanate halogen bonding provides divergent solid state arylation by diaryliodonium cations
X-ray crystallography data revealed the dichotomy of thiocyanate-involving noncovalent
interactions in [Ar1Ar2I](SCN), as reflected in the generation of two types of supramolecular …
interactions in [Ar1Ar2I](SCN), as reflected in the generation of two types of supramolecular …
Key-to-lock halogen bond-based tetragonal pyramidal association of iodonium cations with the lacune rims of beta-octamolybdate
The structure-directing “key-to-lock” interaction of double σ-(IIII)-hole donating iodonium
cations with the O-flanked pseudo-lacune rims of [β-Mo8O26] 4− gives halogen-bonded …
cations with the O-flanked pseudo-lacune rims of [β-Mo8O26] 4− gives halogen-bonded …