The chalcogen bond in crystalline solids: A world parallel to halogen bond

P Scilabra, G Terraneo, G Resnati - Accounts of Chemical …, 2019 - ACS Publications
Conspectus The distribution of the electron density around covalently bonded atoms is
anisotropic, and this determines the presence, on atoms surface, of areas of higher and …

Organic cocrystals: beyond electrical conductivities and field‐effect transistors (FETs)

Y Huang, Z Wang, Z Chen… - Angewandte Chemie …, 2019 - Wiley Online Library
Organic cocrystals based on noncovalent intermolecular interactions (weak interactions)
have aroused interest owing to their unpredicted and versatile chemicophysical properties …

Hypervalent Iodine (III) compounds as biaxial halogen bond donors

F Heinen, E Engelage, CJ Cramer… - Journal of the American …, 2020 - ACS Publications
“Hypervalent” iodine (III) derivatives have been established as powerful reagents in organic
transformations, but so far only a handful of studies have addressed their potential use as …

Iodine (III)‐Based Halogen Bond Donors: Properties and Applications

R Robidas, DL Reinhard, CY Legault… - The Chemical …, 2021 - Wiley Online Library
Halogen bonding, the non‐covalent interaction of Lewis bases with an electron‐deficient
region of halogen substituents, received increased attention recently. Consequently, the …

Zwitterionic iodonium species afford halogen bond-based porous organic frameworks

NS Soldatova, PS Postnikov, DM Ivanov… - Chemical …, 2022 - pubs.rsc.org
Porous architectures characterized by parallel channels arranged in honeycomb or
rectangular patterns are identified in two polymorphic crystals of a zwitterionic 4 …

Noncovalent Chelation by Halogen Bonding in the Design of Metal-Containing Arrays: Assembly of Double σ-Hole Donating Halolium with CuI-Containing O,O …

AV Semenov, SV Baykov, NS Soldatova… - Inorganic …, 2023 - ACS Publications
Five new copper (I) complexes─ composed of the paired dibenzohalolium and [CuL2]−(L=
1, 2, 4-oxadiazolate) counterions in which O, O-atoms of the anion are simultaneously linked …

A Halogen‐Bond‐Driven Artificial Chloride‐Selective Channel Constructed from 5‐Iodoisophthalamide‐based Molecules

R Sharma, S Sarkar, S Chattopadhayay… - Angewandte Chemie …, 2024 - Wiley Online Library
Despite considerable emphasis on advancing artificial ion channels, progress is constrained
by the limited availability of small molecules with the necessary attributes of self‐assembly …

C (sp3) atoms as tetrel bond donors: A crystallographic survey

A Daolio, P Scilabra, G Terraneo, G Resnati - Coordination Chemistry …, 2020 - Elsevier
The σ-hole and π-hole interactions allow for a systematic understanding of some features of
the attractive interactions involving elements of groups 13–18 of the periodic table and of …

Diaryliodonium as a double σ-hole donor: The dichotomy of thiocyanate halogen bonding provides divergent solid state arylation by diaryliodonium cations

NS Soldatova, PS Postnikov, VV Suslonov… - Organic Chemistry …, 2020 - pubs.rsc.org
X-ray crystallography data revealed the dichotomy of thiocyanate-involving noncovalent
interactions in [Ar1Ar2I](SCN), as reflected in the generation of two types of supramolecular …

Key-to-lock halogen bond-based tetragonal pyramidal association of iodonium cations with the lacune rims of beta-octamolybdate

NS Soldatova, AD Radzhabov, DM Ivanov… - Chemical …, 2024 - pubs.rsc.org
The structure-directing “key-to-lock” interaction of double σ-(IIII)-hole donating iodonium
cations with the O-flanked pseudo-lacune rims of [β-Mo8O26] 4− gives halogen-bonded …