Polymers without petrochemicals: sustainable routes to conventional monomers

G Hayes, M Laurel, D MacKinnon, T Zhao… - Chemical …, 2022 - ACS Publications
Access to a wide range of plastic materials has been rationalized by the increased demand
from growing populations and the development of high-throughput production systems …

Biobased vitrimers: Towards sustainable and adaptable performing polymer materials

MA Lucherelli, A Duval, L Avérous - Progress in Polymer Science, 2022 - Elsevier
In the last decades, Covalent Adaptable Networks (CAN) appeared as an innovative
polymer family, able to bridge the gap between thermoplastics and thermosets. CAN rely on …

Biobased covalent adaptable networks: towards better sustainability of thermosets

XL Zhao, PX Tian, YD Li, JB Zeng - Green Chemistry, 2022 - pubs.rsc.org
Thermosets have many advantages such as excellent mechanical properties, dimensional
stability, and chemical and environmental resistance, but suffer from unsustainability …

Dynamically cross‐linking soybean oil and low‐molecular‐weight polylactic acid toward mechanically robust, degradable, and recyclable supramolecular plastics

X Fang, N Tian, W Hu, Y Qing, H Wang… - Advanced Functional …, 2022 - Wiley Online Library
To promote the sustainable development of society, it is important to develop methods for
facile fabrication of bio‐based plastics that are mechanically robust and capable of recycling …

High-Tg and Degradable Isosorbide-Based Polybenzoxazine Vitrimer

A Adjaoud, L Puchot, P Verge - ACS Sustainable Chemistry & …, 2021 - ACS Publications
This work describes new fully bio-based vitrimers prepared from isosorbide, a renewable
sugar-based chemical. Isosorbide was reacted with 4-hydroxypropionic acid …

Ultrastrong, high fire resistance, repairable, and recyclable fluorinated biobased polyimine networks

J Wang, H Ding, P Yu, Z Jia, C Wang, H Wang… - ACS Materials …, 2024 - ACS Publications
Traditional commercial thermosetting materials are currently facing significant challenges in
terms of reprocessing, degradation, and recycling because of a large demand of petroleum …

Circularity in polymers: addressing performance and sustainability challenges using dynamic covalent chemistries

T Yan, AH Balzer, KM Herbert, TH Epps… - Chemical Science, 2023 - pubs.rsc.org
The circularity of current and future polymeric materials is a major focus of fundamental and
applied research, as undesirable end-of-life outcomes and waste accumulation are global …

Covalent adaptable networks from renewable resources: Crosslinked polymers for a sustainable future

S Kamarulzaman, ZM Png, EQ Lim, IZS Lim, Z Li… - Chem, 2023 - cell.com
Covalent adaptable networks (CANs) are crosslinked polymers with dynamic covalent
bonds, which enable these networks to exhibit both the durability of thermosets and the …

Controlling Dynamics of Associative Networks through Primary Chain Length

JJ Lessard, KA Stewart, BS Sumerlin - Macromolecules, 2022 - ACS Publications
Dynamic networks couple the robust nature of thermosets with the shapeability and
recyclability of thermoplastics. Though a wealth of exchange chemistries can be leveraged …

Fully Biobased Vitrimers: Future Direction toward Sustainable Cross‐Linked Polymers

T Vidil, A Llevot - Macromolecular Chemistry and Physics, 2022 - Wiley Online Library
Improving the sustainability of polymer networks is a crucial challenge in polymer science
due to their important role in industry. Their traditional syntheses conflict with several …