Remarkable advances and current state-of-the-art developments in catalytic
hydrophosphination of alkenes and alkynes are reviewed. The challenges in constructing a …

A number of palladacycles containing chiral chelating auxiliaries have been utilized as
efficient catalysts for asymmetric hydrophosphination reactions. In all cases, the chiral …

The first catalytic double hydrophosphination of alkynes was achieved by reaction with
diarylphosphines in the presence of an iron catalyst. The double hydrophosphination …

Our journey in organophosphorus research over the past 26 years is compiled in this
Personal Account. Advances in palladacycle design have engendered a shift in our focus …

This chapter provides an account of the synthesis of a series of chiral tertiary phosphines via
the metal complex-assisted asymmetric hydrophosphination methodology which involves …

A synthetic strategy to generate chiral NC (sp3)-E (E= S, O) pincer complexes incorporating
enhanced stereoprojecting groups at the N-arm site has been established. The synthesis of …

The dissymmetrical chiral bidentate (R)-(+)-1-(diphenylphosphino)-2-(diphenylarsino)
propane was prepared stereoselectively via the novel asymmetric hydroarsination reaction …

A chiral palladacycle has been used successfully to promote the asymmetric
hydrophosphination reactions between the racemic secondary phosphine …

A novel amine ligand, 1-(2, 5-dichlorophenyl)-N, N-dimethylethanamine, was synthesized
from 1-(2, 5-dichlorophenyl) ethanone via a three step synthetic route. Direct ortho …

Abstract Two chiral (–)-diphosphine-digold (I) complexes containing mono-and di-methyl
ester substituted diphosphine ligands have been prepared and structurally characterized …